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题名: Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation
作者: Jia Di Huang1, 2;  Xiang Ping Hu1;  Zhuo Zheng1
关键词: synthesis ;  alpha-phenylethylamine ;  phosphine-triazine ligand ;  Pd-catalyzed allylic alkylation
刊名: CHINESE CHEMICAL LETTERS
发表日期: 2008-03-01
DOI: 10.1016/j.cclet.2007.12.027
卷: 19, 期:3, 页:261-263
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A novel chiral phosphine-triazine ligand was synthesized from chiral alpha-phenylethylamine through a three-step procedure. In a model reaction of Pd-catalyzed allylic alkylation of rac-1,3-diphenylprop-2-en-1-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand. (c) 2007 Zhuo Zheng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
关键词[WOS]: SUBSTITUTION-REACTIONS ;  HYDROBORATION ;  P,N-LIGAND
语种: 英语
WOS记录号: WOS:000256867500004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140766
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Jia Di Huang,Xiang Ping Hu,Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation[J]. CHINESE CHEMICAL LETTERS,2008,19(3):261-263.
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