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Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation
Jia Di Huang1,2; Xiang Ping Hu1; Zhuo Zheng1
关键词Synthesis Alpha-phenylethylamine Phosphine-triazine Ligand Pd-catalyzed Allylic Alkylation
刊名CHINESE CHEMICAL LETTERS
2008-03-01
DOI10.1016/j.cclet.2007.12.027
19期:3页:261-263
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SUBSTITUTION-REACTIONS ; HYDROBORATION ; P,N-LIGAND
英文摘要A novel chiral phosphine-triazine ligand was synthesized from chiral alpha-phenylethylamine through a three-step procedure. In a model reaction of Pd-catalyzed allylic alkylation of rac-1,3-diphenylprop-2-en-1-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand. (c) 2007 Zhuo Zheng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
语种英语
WOS记录号WOS:000256867500004
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140766
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Jia Di Huang,Xiang Ping Hu,Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation[J]. CHINESE CHEMICAL LETTERS,2008,19(3):261-263.
APA Jia Di Huang,Xiang Ping Hu,&Zhuo Zheng.(2008).Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation.CHINESE CHEMICAL LETTERS,19(3),261-263.
MLA Jia Di Huang,et al."Synthesis of novel chiral phosphine-triazine ligand derived from alpha-phenylethylamine for Pd-catalyzed asymmetric allylic alkylation".CHINESE CHEMICAL LETTERS 19.3(2008):261-263.
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