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题名: Efficient I(5 P-2(1/2)) production by the reaction of I-2 with NCl3 flame
作者: Li, Liucheng1, 2;  Duo, Liping1;  Yang, Bailing1
刊名: CHEMISTRY LETTERS
发表日期: 2008-07-05
DOI: 10.1246/cl.2008.738
卷: 37, 期:7, 页:738-739
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: When gaseous iodine was admitted into the NCl3 autodecomposition flame, intense I(5 P-2(1/2)) -> I(5 P-2(3/2)) emission was observed owing to direct pumping of iodine atoms by NCl3 flame. It is found that the chemical environment of NCl3 flame is benign for I(5 P-2(3/2)). The mechanisms of I(5 P-2(1/2)) production in the NCl3/I-2 reactive gas flow are discussed for the first time. It is believed that Frank-Condon favored E-E energy transfer from Cl-2(B) to I(5 P-2(3/2)) and the nearly resonant V-E energy transfer from Cl-2(X, v = 15) to I(5 P-2(3/2)) respond for the production of excited state iodine atoms.
关键词[WOS]: ENERGY-TRANSFER ;  CHEMICAL-LASER ;  I(2P1/2) ;  I(2P3/2)
语种: 英语
WOS记录号: WOS:000258280700032
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140769
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Chem Lasers, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Li, Liucheng,Duo, Liping,Yang, Bailing. Efficient I(5 P-2(1/2)) production by the reaction of I-2 with NCl3 flame[J]. CHEMISTRY LETTERS,2008,37(7):738-739.
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