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题名: Heterogeneous catalysts for olefln cross-metathesis
作者: Li Xin1;  Zhang Weiping1;  Li Xiujie1;  Liu Shenglin1
关键词: olefin cross-metathesis ;  heterogeneous catalysts ;  reaction mechanisms ;  deactivation
刊名: PROGRESS IN CHEMISTRY
发表日期: 2008-08-01
卷: 20, 期:7-8, 页:1021-1031
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Olefin metathesis has been widely used in the fields of petrochemical industry and organic synthesis. It can be classified as ring-opening metathesis, ring-opening metathesis polymerization, ring-closing metathesis and cross-metathesis, etc. Recent developments in the heterogeneous catalysts for olefin cross-metathesis are Summarized in this review. Much attention has been paid not only to the heterogeneous catalysts based on Re, Mo and W, but also to the effects that may influence the catalyst activity, such as the metal oxidation state, structure and dispersion of the active species, properties of the support and the addition of promoters, etc. The reaction mechanisms and possible deactivation routes are also discussed in detail.
关键词[WOS]: SILICA MOLYBDENA CATALYSTS ;  SUPPORTED RHENIUM CATALYSTS ;  IMIDO ALKYLIDENE COMPLEXES ;  PROPENE METATHESIS ;  PROPYLENE METATHESIS ;  ALUMINA CATALYSTS ;  ALKENE METATHESIS ;  TUNGSTEN-OXIDE ;  PHOTOINDUCED METATHESIS ;  MOO3.SIO2 SYSTEMS
语种: 英语
WOS记录号: WOS:000258486600003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140784
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Li Xin,Zhang Weiping,Li Xiujie,et al. Heterogeneous catalysts for olefln cross-metathesis[J]. PROGRESS IN CHEMISTRY,2008,20(7-8):1021-1031.
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