DICP OpenIR
Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds
Qiu, Min; Hu, Xiang-Ping; Wang, Dao-Yong; Deng, Jun; Huang, Jia-Di; Yu, Sai-Bo; Duan, Zheng-Chao; Zheng, Zhuo
关键词Asymmetric Catalysis Hydrogenation Olefins Phosphine-phosphoramidite Ligand
刊名ADVANCED SYNTHESIS & CATALYSIS
2008-06-01
DOI10.1002/adsc.200800152
350期:9页:1413-1418
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CATALYZED ASYMMETRIC HYDROGENATION ; PHOSPHONIC ACID-DERIVATIVES ; ALPHA-AMINO ; MICELLAR MEDIA ; HYDROXY ; COMPLEXES ; QUINAPHOS ; ESTERS
英文摘要We have recently reported a new chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand, (R-c,R-a)-THNAPhos, that is highly efficient in the rhodium-catalyzed asymmetric hydrogenation of a broad range of alpha-enol ester phosphonates. To further demonstrate the utility of THNAPhos in asymmetric hydrogenation, in this paper, we describe its new application in the asymmetric hydrogenation of alpha-dehydroamino acid esters, enamides, dimethyl itaconate and alpha-enamido phosphonates. The results disclosed that the Rh/(R-c,R-a)-THNAPhos complex is highly effective for the enantioselective hydrogenation of these kinds of functionalized C=C olefins, affording the corresponding hydrogenation product in excellent enantioselectivities (normally over 99% ee).
语种英语
WOS记录号WOS:000256976100035
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140797
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Qiu, Min,Hu, Xiang-Ping,Wang, Dao-Yong,et al. Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds[J]. ADVANCED SYNTHESIS & CATALYSIS,2008,350(9):1413-1418.
APA Qiu, Min.,Hu, Xiang-Ping.,Wang, Dao-Yong.,Deng, Jun.,Huang, Jia-Di.,...&Zheng, Zhuo.(2008).Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds.ADVANCED SYNTHESIS & CATALYSIS,350(9),1413-1418.
MLA Qiu, Min,et al."Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds".ADVANCED SYNTHESIS & CATALYSIS 350.9(2008):1413-1418.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Qiu, Min]的文章
[Hu, Xiang-Ping]的文章
[Wang, Dao-Yong]的文章
百度学术
百度学术中相似的文章
[Qiu, Min]的文章
[Hu, Xiang-Ping]的文章
[Wang, Dao-Yong]的文章
必应学术
必应学术中相似的文章
[Qiu, Min]的文章
[Hu, Xiang-Ping]的文章
[Wang, Dao-Yong]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。