中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography
作者: Dong, Xiaoli1, 2;  Wu, Ren'an1;  Dong, Jing1;  Wu, Minghuo1;  Zhu, Yan2;  Zou, Hanfa1
关键词: Capillary electrochromatography ;  Cellulose tris(3,5-dimethylphenylcarbamate) ;  Covalently bonded chiral stationary phase ;  Enantioseparation ;  Silica monolithic column
刊名: JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES
发表日期: 2008-11-01
DOI: 10.1016/j.jchromb.2008.05.019
卷: 875, 期:1, 页:317-322
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Life Sciences & Biomedicine ;  Physical Sciences
类目[WOS]: Biochemical Research Methods ;  Chemistry, Analytical
研究领域[WOS]: Biochemistry & Molecular Biology ;  Chemistry
英文摘要: A chiral capillary monolithic column for capillary electrochromatography (CEC) was prepared by covalent bonding of cellulose tris(3,5-dimethylphenylcarbamate) (CDMPC) on the silica monolithic matrix within the confine of a 50-mu m i.d. bare fused silica capillary. Several pairs of enantiomers including neutral and basic analytes were baseline resolved on the newly prepared chiral capillary monolithic column in CEC with aqueous mobile phases. Fast enantioseparation was achieved due to the favorable dynamic properties of silica monolith. The covalent bonding of CDMPC as the chiral stationary phase for CEC also enabled the use of THF in mobile phase for enantioseparation of prazquantel by overcoming the incompatibility of THF and the physically coated CDMPC on a column. (c) 2008 Published by Elsevier B.V.
关键词[WOS]: CHIRAL STATIONARY-PHASE ;  LIQUID-CHROMATOGRAPHIC ENANTIOSEPARATIONS ;  CHARGED POLYACRYLAMIDE-GELS ;  ENANTIOMERIC SEPARATIONS ;  POLYSACCHARIDE DERIVATIVES ;  VANCOMYCIN ;  TRIS(3,5-DICHLOROPHENYLCARBAMATE) ;  SIZE
语种: 英语
WOS记录号: WOS:000260945800042
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140808
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatograph R&A Ctr, Dalian 116023, Peoples R China
2.Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

Recommended Citation:
Dong, Xiaoli,Wu, Ren'an,Dong, Jing,et al. The covalently bonded cellulose tris(3,5-dimethylphenylcarbamate) on a silica monolithic capillary column for enantioseparation in capillary electrochromatography[J]. JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES,2008,875(1):317-322.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Dong, Xiaoli]'s Articles
 [Wu, Ren'an]'s Articles
 [Dong, Jing]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Dong, Xiaoli]‘s Articles
 [Wu, Ren'an]‘s Articles
 [Dong, Jing]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace