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Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3]
Lv, X-C.2; Gao, X-H.2; Tan, Z. -C.1,3; Li, Y-S.3; Sun, L. -X.1
关键词Adiabatic Calorimetry Low-temperature Heat Capacity 1 Thermal Analysis 2-cyclohexane Dicarboxylic Anhydride
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2008-05-01
DOI10.1007/s10973-007-8445-5
92期:2页:523-527
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]THERMAL-ANALYSIS ; TEMPERATURE ; ACID
英文摘要The molar heat capacity C-p,C-m of 1,2-cyclohexane dicarboxylic anhydride was measured in the temperature range from T=80 to 390 K with a small sample automated adiabatic calorimeter. The melting point T-m, the molar enthalpy Delta H-fus(m) and the entropy Delta S-fus(m) of fusion for the compound were determined to be 303.80 K, 14.71 kJ mol(-1) and 48.43 J K-1 mol(-1), respectively. The thermodynamic functions [H-T-H-273.15] and [S-T-S-273.15] were derived in the temperature range from T=80 to 3 85 K with temperature interval of 5 K. The thermal stability of the compound was investigated by differential scanning calorimeter (DSC) and thermogravimetry (TG), when the process of the mass-loss was due to the evaporation, instead of its thermal decomposition.
语种英语
WOS记录号WOS:000255957400028
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140818
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
2.Liaoning Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Peoples R China
3.Dalian Jiaotong Univ, Coll Environm Sci & Engn, Dalian 116028, Peoples R China
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Lv, X-C.,Gao, X-H.,Tan, Z. -C.,et al. Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3][J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2008,92(2):523-527.
APA Lv, X-C.,Gao, X-H.,Tan, Z. -C.,Li, Y-S.,&Sun, L. -X..(2008).Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3].JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,92(2),523-527.
MLA Lv, X-C.,et al."Molar heat capacity and thermodynamic properties of 1,2-cyclohexane dicarboxylic anhydride [C8H10O3]".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 92.2(2008):523-527.
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