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题名: Organocatalytic highly enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes
作者: Zhou, Wen-Ming1;  Liu, Han1;  Du, Da-Ming1
刊名: ORGANIC LETTERS
发表日期: 2008-07-03
DOI: 10.1021/ol800945e
卷: 10, 期:13, 页:2817-2820
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The first organocatalytic enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes for the direct synthesis of chiral nitroalkylated naphthoquinone derivatives was investigated. Good yields and excellent enantioselectivities (up to > 99% ee) could be achieved. This organocatalytic asymmetric Michael addition provides an efficient route torward the synthesis of optically active functionalized naphthoquinones.
关键词[WOS]: FRIEDEL-CRAFTS ALKYLATION ;  CONJUGATE ADDITION ;  ASYMMETRIC ORGANOCATALYSIS ;  ANTICANCER AGENTS ;  1,4-NAPHTHOQUINONE DERIVATIVES ;  BIFUNCTIONAL ORGANOCATALYSTS ;  CINCHONA ORGANOCATALYSTS ;  CYTOTOXIC EVALUATION ;  MULTIPLE-SCLEROSIS ;  DIPHENYL PHOSPHITE
语种: 英语
WOS记录号: WOS:000257211400051
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140820
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China

Recommended Citation:
Zhou, Wen-Ming,Liu, Han,Du, Da-Ming. Organocatalytic highly enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes[J]. ORGANIC LETTERS,2008,10(13):2817-2820.
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