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题名: Direct hydroxylation of benzene to phenol over a new vanadium-substituted phosphomolybdate as a solid catalyst
作者: Chen, Jiaqi1, 2;  Gao, Shuang1;  Xu, Jie1
关键词: hydroxylation ;  benzene ;  hydrogen peroxide ;  phosphomolybdate
刊名: CATALYSIS COMMUNICATIONS
发表日期: 2008-03-20
DOI: 10.1016/j.catcom.2007.08.010
卷: 9, 期:5, 页:728-733
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: With aqueous hydroxylation as oxidant, benzene was directly hydroxylated to phenol with phenol yield of 12.4% and selectivity of 85.7% over tetramethyl ammonium 11-molybdo-1-vanadophosphates [(CH3)(4)N](4)PMo11VO40 as a solid catalyst, which was testified to be stable and could be recovered and reused with high activity. (c) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: LIQUID-PHASE OXIDATION ;  HYDROGEN-PEROXIDE ;  HETEROPOLYACID CATALYSTS ;  SELECTIVE HYDROXYLATION ;  PALLADIUM MEMBRANE ;  MOLECULAR-OXYGEN ;  NITROUS-OXIDE ;  HETEROPOLYMOLYBDATES
语种: 英语
WOS记录号: WOS:000253450900032
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140836
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Chen, Jiaqi,Gao, Shuang,Xu, Jie. Direct hydroxylation of benzene to phenol over a new vanadium-substituted phosphomolybdate as a solid catalyst[J]. CATALYSIS COMMUNICATIONS,2008,9(5):728-733.
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