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题名: Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols
作者: Zhang Xiao-Peng1, 2;  Lu Shi-Wei1
关键词: selenium ;  aniline ;  thiol ;  carbonylation ;  thiocarbarnate
刊名: CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
发表日期: 2008-06-10
卷: 29, 期:6, 页:1137-1140
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: In order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. Mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. The results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. Selenium could be easily recovered and recycled.
关键词[WOS]: CARBON-MONOXIDE ;  ASSISTED CARBONYLATION ;  HYDROLYSIS ;  MECHANISM
语种: 英语
WOS记录号: WOS:000257176300014
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140838
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
2.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China

Recommended Citation:
Zhang Xiao-Peng,Lu Shi-Wei. Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2008,29(6):1137-1140.
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