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Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols
Zhang Xiao-Peng1,2; Lu Shi-Wei1
关键词Selenium Aniline Thiol Carbonylation Thiocarbarnate
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
2008-06-10
29期:6页:1137-1140
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]CARBON-MONOXIDE ; ASSISTED CARBONYLATION ; HYDROLYSIS ; MECHANISM
英文摘要In order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. Mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. The results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. Selenium could be easily recovered and recycled.
语种英语
WOS记录号WOS:000257176300014
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140838
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
2.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
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Zhang Xiao-Peng,Lu Shi-Wei. Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2008,29(6):1137-1140.
APA Zhang Xiao-Peng,&Lu Shi-Wei.(2008).Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,29(6),1137-1140.
MLA Zhang Xiao-Peng,et al."Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 29.6(2008):1137-1140.
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