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Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols
Zhang Xiao-Peng1,2; Lu Shi-Wei1
KeywordSelenium Aniline Thiol Carbonylation Thiocarbarnate
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
2008-06-10
Volume29Issue:6Pages:1137-1140
Indexed BySCI ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordCARBON-MONOXIDE ; ASSISTED CARBONYLATION ; HYDROLYSIS ; MECHANISM
AbstractIn order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. Mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. The results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. Selenium could be easily recovered and recycled.
Language英语
WOS IDWOS:000257176300014
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140838
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
2.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Recommended Citation
GB/T 7714
Zhang Xiao-Peng,Lu Shi-Wei. Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2008,29(6):1137-1140.
APA Zhang Xiao-Peng,&Lu Shi-Wei.(2008).Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,29(6),1137-1140.
MLA Zhang Xiao-Peng,et al."Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 29.6(2008):1137-1140.
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