中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane
作者: Zhou, Lipeng1;  Xu, Jie1;  Chen, Chen1;  Wang, Feng1;  Li, Xiaoqiang1
关键词: molecular sieves ;  aluminophosphate ;  cyclohexane oxidation ;  molecular oxygen
刊名: JOURNAL OF POROUS MATERIALS
发表日期: 2008-02-01
DOI: 10.1007/s10934-006-9045-7
卷: 15, 期:1, 页:7-12
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Materials Science, Multidisciplinary
研究领域[WOS]: Chemistry ;  Materials Science
英文摘要: Fe, Co, and Mn substituted AlPO-5 molecular sieves, including FeAPO-5, CoAPO-5, MnAPO-5, FeCoAPO-5, FeMnAPO-5, and CoMnAPO-5 were synthesized by hydrothermal method and characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), nitrogen adsorption, and Fourier transform infrared (FT-IR) spectroscopy. The lattice expansions were observed with Fe, Co, and/or Mn substitution of Al atom in AlPO-5. The selective oxidation of cyclohexane to cyclohexanone and cyclohexanol (K/A oil) with molecular oxygen was studied over these catalysts at the reaction temperature of 403 K. The higher activities of the multi-metal substituted AlPO-5, compared to that of single metal substituted AlPO-5, were observed. The underlying reason for the superior activity of the multi-metal substituted AlPO-5 was analyzed.
关键词[WOS]: LOW CONVERSION AUTOXIDATION ;  TRANSITION-METAL IONS ;  PURE CYCLOHEXANE ;  LIQUID-PHASE ;  OXYGEN ;  ALUMINOPHOSPHATE ;  HYDROCARBONS ;  AIR ;  VAPO-5
语种: 英语
WOS记录号: WOS:000251795500002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140843
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Grad Sch, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Zhou, Lipeng,Xu, Jie,Chen, Chen,et al. Synthesis of Fe, Co, and Mn substituted AlPO-5 molecular sieves and their catalytic activities in the selective oxidation of cyclohexane[J]. JOURNAL OF POROUS MATERIALS,2008,15(1):7-12.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhou, Lipeng]'s Articles
 [Xu, Jie]'s Articles
 [Chen, Chen]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhou, Lipeng]‘s Articles
 [Xu, Jie]‘s Articles
 [Chen, Chen]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace