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Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands
Duan, Zheng-Chao1,2; Hu, Xiang-Ping1; Wang, Dao-Yong1,2; Huang, Jia-Di1,2; Yu, Sai-Bo1,2; Deng, Jun1,2; Zheng, Zhuo1
KeywordAlkanephosphonates Asymmetric Catalysis Hydrogenation Monophosphoramidite Ligands Rhodium
Source PublicationADVANCED SYNTHESIS & CATALYSIS
2008-09-01
DOI10.1002/adsc.200800388
Volume350Issue:13Pages:1979-1983
Indexed BySCI ; IC
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Applied ; Chemistry, Organic
WOS Research AreaChemistry
WOS KeywordPHOSPHINE-PHOSPHORAMIDITE LIGANDS ; DEHYDROAMINO ACID-DERIVATIVES ; PHOTO-ARBUZOV REARRANGEMENTS ; ENOL ESTER PHOSPHONATES ; N-H PROTON ; AMINO ACIDS ; REACTIVE IMMUNIZATION ; BENZYL PHOSPHITES ; MICELLAR MEDIA ; ALPHA-HYDROXY
AbstractA series of chiral beta-substituted alkane-phosphonates was synthesized in high enantioselectivities via the first rhodium-catalyzed asymmetric hydrogenation of the corresponding beta-substituted-alpha,beta-unsaturated phosphonates using a ferrocene-derived rnonophosphoramidite ligand, with which up to 99.5% ee have been achieved for the hydrogenation of (E)-substrates and 98.0% ee for (Z)-substrates.
Language英语
WOS IDWOS:000259544300010
Citation statistics
Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140854
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Duan, Zheng-Chao,Hu, Xiang-Ping,Wang, Dao-Yong,et al. Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands[J]. ADVANCED SYNTHESIS & CATALYSIS,2008,350(13):1979-1983.
APA Duan, Zheng-Chao.,Hu, Xiang-Ping.,Wang, Dao-Yong.,Huang, Jia-Di.,Yu, Sai-Bo.,...&Zheng, Zhuo.(2008).Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands.ADVANCED SYNTHESIS & CATALYSIS,350(13),1979-1983.
MLA Duan, Zheng-Chao,et al."Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands".ADVANCED SYNTHESIS & CATALYSIS 350.13(2008):1979-1983.
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