中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands
作者: Duan, Zheng-Chao1, 2;  Hu, Xiang-Ping1;  Wang, Dao-Yong1, 2;  Huang, Jia-Di1, 2;  Yu, Sai-Bo1, 2;  Deng, Jun1, 2;  Zheng, Zhuo1
关键词: alkanephosphonates ;  asymmetric catalysis ;  hydrogenation ;  monophosphoramidite ligands ;  rhodium
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2008-09-01
DOI: 10.1002/adsc.200800388
卷: 350, 期:13, 页:1979-1983
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A series of chiral beta-substituted alkane-phosphonates was synthesized in high enantioselectivities via the first rhodium-catalyzed asymmetric hydrogenation of the corresponding beta-substituted-alpha,beta-unsaturated phosphonates using a ferrocene-derived rnonophosphoramidite ligand, with which up to 99.5% ee have been achieved for the hydrogenation of (E)-substrates and 98.0% ee for (Z)-substrates.
关键词[WOS]: PHOSPHINE-PHOSPHORAMIDITE LIGANDS ;  DEHYDROAMINO ACID-DERIVATIVES ;  PHOTO-ARBUZOV REARRANGEMENTS ;  ENOL ESTER PHOSPHONATES ;  N-H PROTON ;  AMINO ACIDS ;  REACTIVE IMMUNIZATION ;  BENZYL PHOSPHITES ;  MICELLAR MEDIA ;  ALPHA-HYDROXY
语种: 英语
WOS记录号: WOS:000259544300010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140854
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Duan, Zheng-Chao,Hu, Xiang-Ping,Wang, Dao-Yong,et al. Enantioselective synthesis of optically active alkanephosphonates via rhodium-catalyzed asymmetric hydrogenation of beta-substituted alpha,beta-unsaturated phosphonates with ferrocene-based monophosphoramidite ligands[J]. ADVANCED SYNTHESIS & CATALYSIS,2008,350(13):1979-1983.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Duan, Zheng-Chao]'s Articles
 [Hu, Xiang-Ping]'s Articles
 [Wang, Dao-Yong]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Duan, Zheng-Chao]‘s Articles
 [Hu, Xiang-Ping]‘s Articles
 [Wang, Dao-Yong]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace