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Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments
Yue, Xian-Fang; Sun, Ju-Long; Zhou, Can-Hua; Cheng, Shi-Bo; Yin, Hong-Ming; Han, Ke-Li
Source PublicationCHEMICAL PHYSICS LETTERS
2008-02-04
DOI10.1016/j.cplett.2007.12.025
Volume452Issue:1-3Pages:14-19
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS KeywordROTATIONAL REFLECTION PRINCIPLE ; S-2 STATE ; VELOCITY DISTRIBUTION ; PHOTO-DISSOCIATION ; OH FRAGMENT ; ALIGNMENT ; CH3ONO ; TRANSITION ; METHYL ; HONO
AbstractMeasurements of the nascent NO fragments from the photodissociation of gaseous n-butyl nitrite at 266 nm were performed using the one-photon excited laser induced fluorescence technique. The rotational state distributions of the photofragment NO are found to be well characterized by a Gaussian distribution, which indicates that the photolysis process in the S, state is a direct and fast dissociation. The measured relative population of NO v '' = 0:123 is 0.65:0.19:0.11:0.05, respectively. Preferential populations of the NO Pi(+) A-doublet state and F-1((2)Pi(1/2)) spin-orbit state are observed. The TD-DFT calculations of n-butyl nitrite are in good agreement with the experimental results. (c) 2007 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000253804500003
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140897
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yue, Xian-Fang,Sun, Ju-Long,Zhou, Can-Hua,et al. Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments[J]. CHEMICAL PHYSICS LETTERS,2008,452(1-3):14-19.
APA Yue, Xian-Fang,Sun, Ju-Long,Zhou, Can-Hua,Cheng, Shi-Bo,Yin, Hong-Ming,&Han, Ke-Li.(2008).Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments.CHEMICAL PHYSICS LETTERS,452(1-3),14-19.
MLA Yue, Xian-Fang,et al."Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments".CHEMICAL PHYSICS LETTERS 452.1-3(2008):14-19.
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