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Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments
Yue, Xian-Fang; Sun, Ju-Long; Zhou, Can-Hua; Cheng, Shi-Bo; Yin, Hong-Ming; Han, Ke-Li
刊名CHEMICAL PHYSICS LETTERS
2008-02-04
DOI10.1016/j.cplett.2007.12.025
452期:1-3页:14-19
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]ROTATIONAL REFLECTION PRINCIPLE ; S-2 STATE ; VELOCITY DISTRIBUTION ; PHOTO-DISSOCIATION ; OH FRAGMENT ; ALIGNMENT ; CH3ONO ; TRANSITION ; METHYL ; HONO
英文摘要Measurements of the nascent NO fragments from the photodissociation of gaseous n-butyl nitrite at 266 nm were performed using the one-photon excited laser induced fluorescence technique. The rotational state distributions of the photofragment NO are found to be well characterized by a Gaussian distribution, which indicates that the photolysis process in the S, state is a direct and fast dissociation. The measured relative population of NO v '' = 0:123 is 0.65:0.19:0.11:0.05, respectively. Preferential populations of the NO Pi(+) A-doublet state and F-1((2)Pi(1/2)) spin-orbit state are observed. The TD-DFT calculations of n-butyl nitrite are in good agreement with the experimental results. (c) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000253804500003
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140897
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Yue, Xian-Fang,Sun, Ju-Long,Zhou, Can-Hua,et al. Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments[J]. CHEMICAL PHYSICS LETTERS,2008,452(1-3):14-19.
APA Yue, Xian-Fang,Sun, Ju-Long,Zhou, Can-Hua,Cheng, Shi-Bo,Yin, Hong-Ming,&Han, Ke-Li.(2008).Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments.CHEMICAL PHYSICS LETTERS,452(1-3),14-19.
MLA Yue, Xian-Fang,et al."Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments".CHEMICAL PHYSICS LETTERS 452.1-3(2008):14-19.
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