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题名: Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments
作者: Yue, Xian-Fang1;  Sun, Ju-Long1;  Zhou, Can-Hua1;  Cheng, Shi-Bo1;  Yin, Hong-Ming1;  Han, Ke-Li1
刊名: CHEMICAL PHYSICS LETTERS
发表日期: 2008-02-04
DOI: 10.1016/j.cplett.2007.12.025
卷: 452, 期:1-3, 页:14-19
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: Measurements of the nascent NO fragments from the photodissociation of gaseous n-butyl nitrite at 266 nm were performed using the one-photon excited laser induced fluorescence technique. The rotational state distributions of the photofragment NO are found to be well characterized by a Gaussian distribution, which indicates that the photolysis process in the S, state is a direct and fast dissociation. The measured relative population of NO v '' = 0:123 is 0.65:0.19:0.11:0.05, respectively. Preferential populations of the NO Pi(+) A-doublet state and F-1((2)Pi(1/2)) spin-orbit state are observed. The TD-DFT calculations of n-butyl nitrite are in good agreement with the experimental results. (c) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: ROTATIONAL REFLECTION PRINCIPLE ;  S-2 STATE ;  VELOCITY DISTRIBUTION ;  PHOTO-DISSOCIATION ;  OH FRAGMENT ;  ALIGNMENT ;  CH3ONO ;  TRANSITION ;  METHYL ;  HONO
语种: 英语
WOS记录号: WOS:000253804500003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140897
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Yue, Xian-Fang,Sun, Ju-Long,Zhou, Can-Hua,et al. Photodissociation dynamics of n-butyl nitrite at 266 nm: Internal state distributions of nascent NO fragments[J]. CHEMICAL PHYSICS LETTERS,2008,452(1-3):14-19.
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