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题名: Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in the Transfer Hydrogenation of Ketones
作者: Zeng, Fanlong1;  Yu, Zhengkun1, 2
刊名: ORGANOMETALLICS
发表日期: 2008-11-24
DOI: 10.1021/om8006213
卷: 27, 期:22, 页:6025-6028
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Ruthenium(II) complexes bearing a pyridyl-supported pyrazol-3-yl-N-heterocyclic carbene (NNC) ligand were synthesized from the reactions of RuCl(3)center dot 3H(2)O with pyridyl-supported pyrazol-3-yl-imidazolium salts in the presence of carbon monoxide. These Ru(II) complexes have exhibited good to excellent catalytic activity in the transfer hydrogenation of ketones in refluxing 2-propanol. Formation of a coordinatively unsaturated Ru(II) center in the precatalyst is attributed to the high catalytic activity of the Ru(II) complexes.
关键词[WOS]: SUZUKI-MIYAURA ;  METATHESIS ;  COORDINATION ;  CHEMISTRY ;  ALCOHOLS ;  HYDRIDE ;  NHC
语种: 英语
WOS记录号: WOS:000260791400035
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/140905
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Zeng, Fanlong,Yu, Zhengkun. Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in the Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2008,27(22):6025-6028.
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