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Nanocomposite MFI-alumina membranes via pore-plugging synthesis: Genesis of the zeolite material
Li, Y.1,2; Pera-Titus, M.1; Xiong, G.2; Yang, W.2; Landrivon, E.1; Miachon, S.1; Dalmon, J. -A.1
关键词Mfi Zeolite Membrane Nanocomposite Film Mass Transfer
刊名JOURNAL OF MEMBRANE SCIENCE
2008-12-01
DOI10.1016/j.memsci.2008.09.030
325期:2页:973-981
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Engineering, Chemical ; Polymer Science
研究领域[WOS]Engineering ; Polymer Science
关键词[WOS]SILICALITE-1 MEMBRANE ; TEMPLATE-REMOVAL ; SEPARATION ; REACTOR ; PERVAPORATION ; PERMEATION ; DIFFUSION ; PROPANE ; SIMULATION ; PROSPECTS
英文摘要This paper presents a study of MFI-type zeolite crystal growth during hydrothermal synthesis of nanocomposite MFI-alumina membranes by the pore-plugging method, using the standard protocol described in a previous study [S. Miachon, E. Landrivon, M. Aouine, Y. Sun, I. Kumakiri, Y. Li, O. Pachtova Prokopova, N. Guilhaume, A. Giroir-Fendler, H. Mozzanega, J.-A. Dalmon, Nanocomposite MFI-alumina membranes via pore-plugging synthesis: specific transport and separation properties, J. Membr. Sci. 281 (2006) 228]. To this aim, the materials have been characterized by SEMI, EDX, pure H2 gas permeance and n-butane/H2 mixture separation at different stages of the synthesis. The effect of synthesis time in the range of 4-89h and the effect of a 9-h interruption after a 8-h hydrothermal synthesis have been surveyed, as well as the mean pore size and the alumina phase of the support inner layer. Our results suggest that an interruption during the synthesis is necessary to allow the zeolite precursor to diffuse into the Support pores. This diffusion leads to a further growth of zeolite crystals into the support matrix without formation of a continuous zeolite film on top of the support, as is usually reported in the literature. The zeolite crystals are fully embedded into the support top layer after at least 53-h synthesis time. leading to high quality membranes in only one synthesis run. The nanocomposite MFI-alumina architecture at the nanoscale has important consequences in improving the gas separation performance of this kind of materials when compared to more conventional film-like structures. A method based on gas transport measurements has been used to determine the effective thickness of the separating material. (C) 2008 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000262946800056
引用统计
被引频次:37[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/140969
专题中国科学院大连化学物理研究所
作者单位1.Univ Lyon, IRCELYON, UMR CNRS 5256, F-69626 Villeurbanne, France
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Li, Y.,Pera-Titus, M.,Xiong, G.,et al. Nanocomposite MFI-alumina membranes via pore-plugging synthesis: Genesis of the zeolite material[J]. JOURNAL OF MEMBRANE SCIENCE,2008,325(2):973-981.
APA Li, Y..,Pera-Titus, M..,Xiong, G..,Yang, W..,Landrivon, E..,...&Dalmon, J. -A..(2008).Nanocomposite MFI-alumina membranes via pore-plugging synthesis: Genesis of the zeolite material.JOURNAL OF MEMBRANE SCIENCE,325(2),973-981.
MLA Li, Y.,et al."Nanocomposite MFI-alumina membranes via pore-plugging synthesis: Genesis of the zeolite material".JOURNAL OF MEMBRANE SCIENCE 325.2(2008):973-981.
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