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Thermal stability and glass transition behavior of PANI/alpha-Al(2)O(3) composites
Qi, Y. -N.2,3; Xu, F.2; Sun, L. -X.2; Zeng, J. -L.2,3; Liu, Y. -Y.2,3
KeywordGlass Transition Modulated Differential Scanning Calorimetry Pani/alpha-al(2)o(3) Composite Thermal Stability
Source PublicationJOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2008-11-01
DOI10.1007/s10973-007-8626-2
Volume94Issue:2Pages:553-557
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordDISPERSIBLE CONDUCTING NANOCOMPOSITES ; POLY(METHYL METHACRYLATE) ; NANOPARTICLE COMPOSITE ; DOPED POLYANILINE ; POLYMER ; SILICA ; ROUTE ; POLY(N-VINYLCARBAZOLE) ; OXIDE
AbstractPolyaniline/alpha-Al(2)O(3) (PANI/alpha-Al(2)O(3)) composites were synthesized by in situ polymerization through ammonium persulfate ((NH(4))(2)S(2)O(8), APS) oxidized aniline using HCl as dopant. XRD and FTIR were used to characterize the PANI/alpha-Al(2)O(3) composites. The thermal stabilities and glass transition temperature (T (g)) of PANI/alpha-Al(2)O(3) composites were tested using thermogravimetric (TG) method and modulated differential scanning calorimetry (MDSC) technique. The results of TG showed that the thermal stability of PANI/alpha-Al(2)O(3) composite increased and then decreased with the increase in alpha-Al(2)O(3) content. The derivative thermogravimetry (DTG) curves showed one step degradation of PANI when the alpha-Al(2)O(3) content was lower than 52.5 mass%, and exhibited two steps degradation when the alpha-Al(2)O(3) content was higher than 63.6 mass%. The MDSC curves showed that the T (g) of PANI/alpha-Al(2)O(3) composites increased and then decreased with the augment of alpha-Al(2)O(3) for the interaction between PANI chains and the surface of alpha-Al(2)O(3).
Language英语
WOS IDWOS:000260878000036
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/140985
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Inst Chem Phys Chinese Acad Sci Zhongshan, Mat & Thermochemistry Lab, Dalian, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Educ Sch Chinese Acad Sci, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Qi, Y. -N.,Xu, F.,Sun, L. -X.,et al. Thermal stability and glass transition behavior of PANI/alpha-Al(2)O(3) composites[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2008,94(2):553-557.
APA Qi, Y. -N.,Xu, F.,Sun, L. -X.,Zeng, J. -L.,&Liu, Y. -Y..(2008).Thermal stability and glass transition behavior of PANI/alpha-Al(2)O(3) composites.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,94(2),553-557.
MLA Qi, Y. -N.,et al."Thermal stability and glass transition behavior of PANI/alpha-Al(2)O(3) composites".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 94.2(2008):553-557.
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