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Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions
Yin Jianzhong1; Ma Xiaorong1; Zhang Xianzhen1; Wang Aiqin2
关键词Carbon Dioxide Expanded Liquids Solubility Enhancement Thermodynamic Properties Chemical Reactions
刊名PROGRESS IN CHEMISTRY
2008-09-01
20期:9页:1251-1262
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]TEMPERATURE IONIC LIQUIDS ; FLUID-PHASE EQUILIBRIA ; CO2-EXPANDED LIQUIDS ; COMPRESSED CO2 ; TERNARY-SYSTEM ; ENANTIOSELECTIVE HYDROGENATION ; ASYMMETRIC HYDROGENATION ; SELECTIVE HYDROGENATION ; HETEROGENEOUS CATALYSIS ; SUPERCRITICAL FLUIDS
英文摘要Carbon dioxide expanded liquids (CXLs) have been considered as a kind of environmentally benign solvents. They often present some unique features such as high gas solubility, good mass transfer property, low viscosity, mild operation conditions, as well as less employment of organic solvents. So they are given more and more attentions by chemists and chemical engineering scientists. This paper reviews the recent studies on the volume expansibility, phase equilibrium thermodynamics, mass transfer properties, acidities, and conductivities of CXLs, and summarizes the chemical reactions based on the CXLs, including hydrogenation, hydroformylation and oxidation etc. Finally, the existing problems associated with the CXLs are analyzed and the research directions of CXLs in future are also pointed out.
语种英语
WOS记录号WOS:000259465900002
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141025
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,et al. Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions[J]. PROGRESS IN CHEMISTRY,2008,20(9):1251-1262.
APA Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,&Wang Aiqin.(2008).Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions.PROGRESS IN CHEMISTRY,20(9),1251-1262.
MLA Yin Jianzhong,et al."Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions".PROGRESS IN CHEMISTRY 20.9(2008):1251-1262.
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