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题名: Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions
作者: Yin Jianzhong1;  Ma Xiaorong1;  Zhang Xianzhen1;  Wang Aiqin2
关键词: carbon dioxide expanded liquids ;  solubility enhancement ;  thermodynamic properties ;  chemical reactions
刊名: PROGRESS IN CHEMISTRY
发表日期: 2008-09-01
卷: 20, 期:9, 页:1251-1262
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Carbon dioxide expanded liquids (CXLs) have been considered as a kind of environmentally benign solvents. They often present some unique features such as high gas solubility, good mass transfer property, low viscosity, mild operation conditions, as well as less employment of organic solvents. So they are given more and more attentions by chemists and chemical engineering scientists. This paper reviews the recent studies on the volume expansibility, phase equilibrium thermodynamics, mass transfer properties, acidities, and conductivities of CXLs, and summarizes the chemical reactions based on the CXLs, including hydrogenation, hydroformylation and oxidation etc. Finally, the existing problems associated with the CXLs are analyzed and the research directions of CXLs in future are also pointed out.
关键词[WOS]: TEMPERATURE IONIC LIQUIDS ;  FLUID-PHASE EQUILIBRIA ;  CO2-EXPANDED LIQUIDS ;  COMPRESSED CO2 ;  TERNARY-SYSTEM ;  ENANTIOSELECTIVE HYDROGENATION ;  ASYMMETRIC HYDROGENATION ;  SELECTIVE HYDROGENATION ;  HETEROGENEOUS CATALYSIS ;  SUPERCRITICAL FLUIDS
语种: 英语
WOS记录号: WOS:000259465900002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141025
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,et al. Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions[J]. PROGRESS IN CHEMISTRY,2008,20(9):1251-1262.
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