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Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions
Yin Jianzhong1; Ma Xiaorong1; Zhang Xianzhen1; Wang Aiqin2
KeywordCarbon Dioxide Expanded Liquids Solubility Enhancement Thermodynamic Properties Chemical Reactions
Source PublicationPROGRESS IN CHEMISTRY
2008-09-01
Volume20Issue:9Pages:1251-1262
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordTEMPERATURE IONIC LIQUIDS ; FLUID-PHASE EQUILIBRIA ; CO2-EXPANDED LIQUIDS ; COMPRESSED CO2 ; TERNARY-SYSTEM ; ENANTIOSELECTIVE HYDROGENATION ; ASYMMETRIC HYDROGENATION ; SELECTIVE HYDROGENATION ; HETEROGENEOUS CATALYSIS ; SUPERCRITICAL FLUIDS
AbstractCarbon dioxide expanded liquids (CXLs) have been considered as a kind of environmentally benign solvents. They often present some unique features such as high gas solubility, good mass transfer property, low viscosity, mild operation conditions, as well as less employment of organic solvents. So they are given more and more attentions by chemists and chemical engineering scientists. This paper reviews the recent studies on the volume expansibility, phase equilibrium thermodynamics, mass transfer properties, acidities, and conductivities of CXLs, and summarizes the chemical reactions based on the CXLs, including hydrogenation, hydroformylation and oxidation etc. Finally, the existing problems associated with the CXLs are analyzed and the research directions of CXLs in future are also pointed out.
Language英语
WOS IDWOS:000259465900002
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141025
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,et al. Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions[J]. PROGRESS IN CHEMISTRY,2008,20(9):1251-1262.
APA Yin Jianzhong,Ma Xiaorong,Zhang Xianzhen,&Wang Aiqin.(2008).Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions.PROGRESS IN CHEMISTRY,20(9),1251-1262.
MLA Yin Jianzhong,et al."Thermodynamic properties of carbon dioxide expanded liquids and applications in chemical reactions".PROGRESS IN CHEMISTRY 20.9(2008):1251-1262.
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