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Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)
Zhang, J.1,2; Zeng, J. L.1,2; Liu, Y. Y.1; Sun, L. X.1,2; Xu, F.; You, W. S.3; Sawada, Y.4
关键词Apparent Activation Energy Kinetic Model Tg-dtg Thermal Decomposition
刊名JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
2008
DOI10.1007/s10973-007-8494-9
91期:1页:189-193
收录类别SCI ; ISTP
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Analytical ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]METAL-ORGANIC FRAMEWORK ; THERMOGRAVIMETRIC DATA ; COORDINATION POLYMERS ; DESIGN
英文摘要Pb(1,4-BDC)center dot(DMF)(H2O) (1,4-BDC=1,4-benzenedicarboxylate; DMF=dimethylformamide) has been synthesized and investigated by elemental analysis, FTIR spectroscopy, thermogravimetry (TG), derivative thermogravimetry (DTG). TG-DTG curves show that the thermal decomposition occurs in four stages and the corresponding apparent activation energies were calculated with the Ozawa-Flynn-Wall (OFW) and the Friedman methods. The most probable kinetic model function of the dehydration reaction of the compound has been estimated by the Coats-Redfern integral and the Achar-Bridly-Sharp differential methods in this study.
语种英语
WOS记录号WOS:000252889200028
引用统计
被引频次:18[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141027
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.Tokyo Polytech Univ, Fac Engn, Dept Nanochem, Atsugi, Kanagawa 2430297, Japan
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GB/T 7714
Zhang, J.,Zeng, J. L.,Liu, Y. Y.,et al. Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2008,91(1):189-193.
APA Zhang, J..,Zeng, J. L..,Liu, Y. Y..,Sun, L. X..,Xu, F..,...&Sawada, Y..(2008).Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O).JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,91(1),189-193.
MLA Zhang, J.,et al."Thermal decomposition kinetics of the synthetic complex Pb(1,4-BDC)center dot(DMF)(H2O)".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 91.1(2008):189-193.
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