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题名: Advances in the synthesis of thiocarbamates
作者: Zhang Xiaopeng1, 2;  Jing Huanzhi1;  Miao Jianghuan1;  Lu Shiwei2
关键词: thiocarbamates ;  carbonylation ;  selenium catalyst
刊名: PROGRESS IN CHEMISTRY
发表日期: 2008-08-01
卷: 20, 期:7-8, 页:1102-1107
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Thiocarbamates, a type of compounds containing many functional groups and possessing bioactivity, have been widely applied in medicine, biology and agricultural chemicals. In this paper, the main methods to synthesize thiocarbamates such as hydrolysis or-alcoholysis of thiocyanate, rearrangement reaction, phosgene derivatives method and carbonylation of nitro compounds or amines are summarized. Their advantages and disadvantages are also compared. It is pointed out that selenium-catalyzed carbonylation of nitro compounds or amines with thiols to thiocarbamates is a promising method which is characterized by benign environment, high atomic economy, and "one-pot" approach.
关键词[WOS]: OXIDATIVE-REDUCTIVE CARBONYLATION ;  SELENIUM-CATALYZED SYNTHESIS ;  HUMAN-LEUKOCYTE ELASTASE ;  CARBON-MONOXIDE ;  ALDEHYDE DEHYDROGENASE ;  ELEMENTAL SULFUR ;  ALLYLIC THIOLS ;  ALKYL-HALIDES ;  HERBICIDES ;  AMINES
语种: 英语
WOS记录号: WOS:000258486600012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141033
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China

Recommended Citation:
Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,et al. Advances in the synthesis of thiocarbamates[J]. PROGRESS IN CHEMISTRY,2008,20(7-8):1102-1107.
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