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Advances in the synthesis of thiocarbamates
Zhang Xiaopeng1,2; Jing Huanzhi1; Miao Jianghuan1; Lu Shiwei2
KeywordThiocarbamates Carbonylation Selenium Catalyst
Source PublicationPROGRESS IN CHEMISTRY
2008-08-01
Volume20Issue:7-8Pages:1102-1107
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordOXIDATIVE-REDUCTIVE CARBONYLATION ; SELENIUM-CATALYZED SYNTHESIS ; HUMAN-LEUKOCYTE ELASTASE ; CARBON-MONOXIDE ; ALDEHYDE DEHYDROGENASE ; ELEMENTAL SULFUR ; ALLYLIC THIOLS ; ALKYL-HALIDES ; HERBICIDES ; AMINES
AbstractThiocarbamates, a type of compounds containing many functional groups and possessing bioactivity, have been widely applied in medicine, biology and agricultural chemicals. In this paper, the main methods to synthesize thiocarbamates such as hydrolysis or-alcoholysis of thiocyanate, rearrangement reaction, phosgene derivatives method and carbonylation of nitro compounds or amines are summarized. Their advantages and disadvantages are also compared. It is pointed out that selenium-catalyzed carbonylation of nitro compounds or amines with thiols to thiocarbamates is a promising method which is characterized by benign environment, high atomic economy, and "one-pot" approach.
Language英语
WOS IDWOS:000258486600012
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141033
Collection中国科学院大连化学物理研究所
Affiliation1.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
Recommended Citation
GB/T 7714
Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,et al. Advances in the synthesis of thiocarbamates[J]. PROGRESS IN CHEMISTRY,2008,20(7-8):1102-1107.
APA Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,&Lu Shiwei.(2008).Advances in the synthesis of thiocarbamates.PROGRESS IN CHEMISTRY,20(7-8),1102-1107.
MLA Zhang Xiaopeng,et al."Advances in the synthesis of thiocarbamates".PROGRESS IN CHEMISTRY 20.7-8(2008):1102-1107.
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