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Advances in the synthesis of thiocarbamates
Zhang Xiaopeng1,2; Jing Huanzhi1; Miao Jianghuan1; Lu Shiwei2
关键词Thiocarbamates Carbonylation Selenium Catalyst
刊名PROGRESS IN CHEMISTRY
2008-08-01
20期:7-8页:1102-1107
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]OXIDATIVE-REDUCTIVE CARBONYLATION ; SELENIUM-CATALYZED SYNTHESIS ; HUMAN-LEUKOCYTE ELASTASE ; CARBON-MONOXIDE ; ALDEHYDE DEHYDROGENASE ; ELEMENTAL SULFUR ; ALLYLIC THIOLS ; ALKYL-HALIDES ; HERBICIDES ; AMINES
英文摘要Thiocarbamates, a type of compounds containing many functional groups and possessing bioactivity, have been widely applied in medicine, biology and agricultural chemicals. In this paper, the main methods to synthesize thiocarbamates such as hydrolysis or-alcoholysis of thiocyanate, rearrangement reaction, phosgene derivatives method and carbonylation of nitro compounds or amines are summarized. Their advantages and disadvantages are also compared. It is pointed out that selenium-catalyzed carbonylation of nitro compounds or amines with thiols to thiocarbamates is a promising method which is characterized by benign environment, high atomic economy, and "one-pot" approach.
语种英语
WOS记录号WOS:000258486600012
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141033
专题中国科学院大连化学物理研究所
作者单位1.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
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Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,et al. Advances in the synthesis of thiocarbamates[J]. PROGRESS IN CHEMISTRY,2008,20(7-8):1102-1107.
APA Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,&Lu Shiwei.(2008).Advances in the synthesis of thiocarbamates.PROGRESS IN CHEMISTRY,20(7-8),1102-1107.
MLA Zhang Xiaopeng,et al."Advances in the synthesis of thiocarbamates".PROGRESS IN CHEMISTRY 20.7-8(2008):1102-1107.
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