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Organocatalytic Oxidative Dehydrogenation of Dihydroarenes by Dioxygen Using 2,3-Dichloro-5,6-dicyano-benzoquinone (DDQ) and NaNO2
Zhang, Wei1,2; Ma, Hong1; Zhou, Lipeng3; Sun, Zhiqiang1; Du, Zhongtian1; Miao, Hong1; Xu, Jie1
KeywordOxidative Dehydrogenation Ddq Dioxygen Redox Couples
Source PublicationMOLECULES
2008-12-01
DOI10.3390/molecules13123236
Volume13Issue:12Pages:3236-3245
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordAEROBIC OXIDATION ; MOLECULAR-OXYGEN ; BENZYL ETHERS ; EFFICIENT ; HYDROCARBONS ; AROMATIZATION ; DEPROTECTION ; CATALYSTS ; QUINONES ; ALCOHOLS
AbstractThe oxidative dehydrogenation of dihydroarenes catalyzed by 2,3-dichloro- 5,6-dicyano-benzoquinone(DDQ) and NaNO2 with dioxygen is reported. The combination of DDQ and NaNO2 showed high efficiency and high selectivity, compared with other benzoquinones and anthraquinones, e. g., >99% conversion of 9,10-dihydroanthracene with 99% selectivity for anthracene can be obtained at 120 degrees C under 1.3 MPa O-2 for 8 h. Excellent results were achieved in the oxidative dehydrogenation of variety of dihydroarenes.
Language英语
WOS IDWOS:000261948300025
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141043
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Zhengzhou Univ, Dept Chem, Inst Catalysis, Zhengzhou 450001, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Wei,Ma, Hong,Zhou, Lipeng,et al. Organocatalytic Oxidative Dehydrogenation of Dihydroarenes by Dioxygen Using 2,3-Dichloro-5,6-dicyano-benzoquinone (DDQ) and NaNO2[J]. MOLECULES,2008,13(12):3236-3245.
APA Zhang, Wei.,Ma, Hong.,Zhou, Lipeng.,Sun, Zhiqiang.,Du, Zhongtian.,...&Xu, Jie.(2008).Organocatalytic Oxidative Dehydrogenation of Dihydroarenes by Dioxygen Using 2,3-Dichloro-5,6-dicyano-benzoquinone (DDQ) and NaNO2.MOLECULES,13(12),3236-3245.
MLA Zhang, Wei,et al."Organocatalytic Oxidative Dehydrogenation of Dihydroarenes by Dioxygen Using 2,3-Dichloro-5,6-dicyano-benzoquinone (DDQ) and NaNO2".MOLECULES 13.12(2008):3236-3245.
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