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题名: Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O
作者: Li, Jing1;  Meng, Lei1;  Sun, Zhen-Gang1;  Liu, Zhong-min2;  Zhao, Yan1;  Zhang, Jing1;  Zhu, Yan-Yu1;  Lu, Xin1;  Liu, Lei1;  Zhang, Na1
关键词: metal phosphonates ;  crystal structure ;  hydrothermal synthesis ;  zinc
刊名: INORGANIC CHEMISTRY COMMUNICATIONS
发表日期: 2008-02-01
DOI: 10.1016/j.inoche.2007.11.023
卷: 11, 期:2, 页:211-214
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: A new 3D porous zinc phosphonate, Zn-6(HL)(4)center dot 6H(2)O 1 (H4L = C6H11N(CH2PO3H2)(2)) has been synthesized by hydrothermal reaction at 180 degrees C and structurally characterized by X-ray diffraction as well as by infrared spectroscopy, elemental and thermogravimetric analysis. The structure of compound 1 features a 3D open-framework built from ZnO4 tetrahedra linked together by bridging phosphonate groups. Each zinc cation is tetrahedrally coordinated by four phosphonate oxygen atoms from four ligands, each of which connects with six zinc atoms, resulting in channel systems of different size. (C) 2007 Elsevier B.V. All rights reserved.
关键词[WOS]: METAL PHOSPHONATES ;  HYDROTHERMAL SYNTHESIS ;  MAGNETIC-PROPERTIES ;  HELICAL CHANNELS ;  LAYER STRUCTURE ;  DOUBLE-CHAIN ;  DIPHOSPHONATES
语种: 英语
WOS记录号: WOS:000253791200019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141085
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Liaoning Normal Univ, Inst Chem Funct Mat, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Nat Gas Chem & Appl Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Li, Jing,Meng, Lei,Sun, Zhen-Gang,et al. Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2008,11(2):211-214.
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