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Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O
Li, Jing1; Meng, Lei1; Sun, Zhen-Gang1; Liu, Zhong-min2; Zhao, Yan1; Zhang, Jing1; Zhu, Yan-Yu1; Lu, Xin1; Liu, Lei1; Zhang, Na1
关键词Metal Phosphonates Crystal Structure Hydrothermal Synthesis Zinc
刊名INORGANIC CHEMISTRY COMMUNICATIONS
2008-02-01
DOI10.1016/j.inoche.2007.11.023
11期:2页:211-214
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]METAL PHOSPHONATES ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; HELICAL CHANNELS ; LAYER STRUCTURE ; DOUBLE-CHAIN ; DIPHOSPHONATES
英文摘要A new 3D porous zinc phosphonate, Zn-6(HL)(4)center dot 6H(2)O 1 (H4L = C6H11N(CH2PO3H2)(2)) has been synthesized by hydrothermal reaction at 180 degrees C and structurally characterized by X-ray diffraction as well as by infrared spectroscopy, elemental and thermogravimetric analysis. The structure of compound 1 features a 3D open-framework built from ZnO4 tetrahedra linked together by bridging phosphonate groups. Each zinc cation is tetrahedrally coordinated by four phosphonate oxygen atoms from four ligands, each of which connects with six zinc atoms, resulting in channel systems of different size. (C) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000253791200019
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141085
专题中国科学院大连化学物理研究所
作者单位1.Liaoning Normal Univ, Inst Chem Funct Mat, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Nat Gas Chem & Appl Catalysis, Dalian 116023, Peoples R China
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Li, Jing,Meng, Lei,Sun, Zhen-Gang,et al. Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2008,11(2):211-214.
APA Li, Jing.,Meng, Lei.,Sun, Zhen-Gang.,Liu, Zhong-min.,Zhao, Yan.,...&Zhang, Na.(2008).Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O.INORGANIC CHEMISTRY COMMUNICATIONS,11(2),211-214.
MLA Li, Jing,et al."Synthesis, crystal structure and characterizations of a new 3D porous zinc phosphonate: Zn-6[(O3PCH2)(2)NHC6H11](4) center dot 6H(2)O".INORGANIC CHEMISTRY COMMUNICATIONS 11.2(2008):211-214.
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