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题名: A toluene guest in a poly(heteronuclear) complex host of ferrocenyl-(CH2)(2)-bridged bis(pyrazole)
作者: Tan, Weiqiang1;  Yu, Zhengkun1, 2;  He, Wei1;  Wang, Liandi1;  Sun, Jie2;  Chen, Jinzhu1
刊名: ORGANOMETALLICS
发表日期: 2008-10-13
DOI: 10.1021/om800704a
卷: 27, 期:19, 页:4833-4836
收录类别: SCI ;  IC
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Reactions of ferrocenyl-(CH2)(n)-bridged bis(pyrazoles) with nickelocene afforded inter- and intramolecular dimeric poly(heteronuclear) cyclopentadienylnickel(II) complexes com which a novel toluene-embodied guest-host system was obtained by pi-interaction. The present paper has demonstrated a new class of potentially useful organometallic building blocks for supramolecular assembly and the first example of a pyrazolato ligand exhibiting a charge transfer type pi-interaction.
关键词[WOS]: PILLARED COORDINATION CAGES ;  STRUCTURAL-CHARACTERIZATION ;  TRANSFER HYDROGENATION ;  CATALYTIC-ACTIVITY ;  CRYSTAL-STRUCTURES ;  BUILDING-BLOCK ;  METAL ;  FERROCENYL ;  LIGANDS ;  DERIVATIVES
语种: 英语
WOS记录号: WOS:000259604200004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141092
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Tan, Weiqiang,Yu, Zhengkun,He, Wei,et al. A toluene guest in a poly(heteronuclear) complex host of ferrocenyl-(CH2)(2)-bridged bis(pyrazole)[J]. ORGANOMETALLICS,2008,27(19):4833-4836.
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