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Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction
Jia Li1; Yu Hong-Wei2; Tong Qing-Song1; Shi Ji-Cheng1,3; Jin Zi-Lin
关键词Phosphine Oxygen-functionalizing Pd Catalyst C-c Bond-forming Reaction Biaryl
刊名CHINESE JOURNAL OF ORGANIC CHEMISTRY
2008-06-01
28期:6页:1115-1118
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CROSS-COUPLING REACTIONS ; TRANSITION-METAL-COMPLEXES ; ARYL CHLORIDES ; EFFICIENT ; BROMIDES ; SALT ; AMINATION ; SYSTEMS ; HECK
英文摘要Ferrocenyl phosphines with methoxy and hydroxy groups have been synthesized and evaluated as supporting ligands in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. It was found that the phosphine having methoxy group as supporting ligand afforded better palladium catalyst with Pd(OAc)(2), which can catalyze electron-rich aryl. bromides and electron-deficient aryl chlorides to couple with phenylboronic acid to form the corresponding biaryls in high yields.
语种英语
WOS记录号WOS:000257409400028
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141097
专题中国科学院大连化学物理研究所
作者单位1.Fujian Normal Univ, Coll Chem & Mat Sci, Key Lab Polymer Mat Fujian Prov, Fuzhou 350007, Peoples R China
2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Jia Li,Yu Hong-Wei,Tong Qing-Song,et al. Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2008,28(6):1115-1118.
APA Jia Li,Yu Hong-Wei,Tong Qing-Song,Shi Ji-Cheng,&Jin Zi-Lin.(2008).Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction.CHINESE JOURNAL OF ORGANIC CHEMISTRY,28(6),1115-1118.
MLA Jia Li,et al."Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction".CHINESE JOURNAL OF ORGANIC CHEMISTRY 28.6(2008):1115-1118.
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