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题名: Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction
作者: Jia Li1;  Yu Hong-Wei2;  Tong Qing-Song1;  Shi Ji-Cheng1, 3;  Jin Zi-Lin
关键词: phosphine ;  oxygen-functionalizing ;  Pd catalyst ;  C-C bond-forming reaction ;  biaryl
刊名: CHINESE JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2008-06-01
卷: 28, 期:6, 页:1115-1118
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Ferrocenyl phosphines with methoxy and hydroxy groups have been synthesized and evaluated as supporting ligands in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction. It was found that the phosphine having methoxy group as supporting ligand afforded better palladium catalyst with Pd(OAc)(2), which can catalyze electron-rich aryl. bromides and electron-deficient aryl chlorides to couple with phenylboronic acid to form the corresponding biaryls in high yields.
关键词[WOS]: CROSS-COUPLING REACTIONS ;  TRANSITION-METAL-COMPLEXES ;  ARYL CHLORIDES ;  EFFICIENT ;  BROMIDES ;  SALT ;  AMINATION ;  SYSTEMS ;  HECK
语种: 英语
WOS记录号: WOS:000257409400028
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141097
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Fujian Normal Univ, Coll Chem & Mat Sci, Key Lab Polymer Mat Fujian Prov, Fuzhou 350007, Peoples R China
2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Jia Li,Yu Hong-Wei,Tong Qing-Song,et al. Application of oxygen-functionalized phosphines as supporting ligands in the palladium-catalyzed Suzuki-Miyaura reaction[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2008,28(6):1115-1118.
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