DICP OpenIR
Effects of carbonization conditions on the properties of coal-based microfiltration carbon membranes
Song, Chengwen1; Wang, Tonghua1; Qiu, Jieshan1; Cao, Yiming2; Cai, Tianxi1
KeywordCarbonization Coal Carbon Membranes Microfiltration Pore Structure
Source PublicationJOURNAL OF POROUS MATERIALS
2008-02-01
DOI10.1007/s10934-006-9044-8
Volume15Issue:1Pages:1-6
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Materials Science
WOS KeywordPYROLYSIS CONDITIONS ; GAS SEPARATION ; PHENOLIC RESIN ; POLYIMIDE ; WATER
AbstractCarbon membranes, a novel porous inorganic membrane, have considerable potential applications in many industrial fields owing to their better stability in aggressive and adverse environments. However, the high cost of precursor materials has hampered their wide applications on commercial scale. In this study, coal, a cheap material, is used to prepare the tubular microfiltration carbon membranes. The effects of carbonization conditions on the properties of coal-based carbon membrane were investigated by the variation of the weight loss, shrinkage ratio of tube size and pore structure characteristics during carbonization. The results show that carbonization conditions greatly affect the properties of coal-based carbon membranes. The carbon membranes carbonized in the inert gases have more "open" porous structure and high gas flux compared to those carbonized in vacuum which makes the carbon membrane possess smaller pores and low gas flux. The carbonization temperature plays an important role in the determination of the pore structure and densification of carbon matrix. At the temperature below 600 degrees C, the pore structure and carbon matrix of carbon membrane are formed with more than 95% of the total weight loss and only 48% of the total size shrinkage ratio. The matrix of carbon membrane gets more compact with the temperature increasing from 600 degrees C to 900 degrees C, in which the size shrinkage ratio is up to 52% with only 5% of the total weight loss. The low heating rate should favor the preparation of the carbon membranes with small average pore size and narrow pore size distribution, and the high gas flow rate can produce the carbon membranes with large average pore size and high porosity.
Language英语
WOS IDWOS:000251795500001
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141104
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Univ Technol, Sch Chem Engn, Dept Mat Sci & Chem Engn, Carbon Res Lab,State Key Lab Fine Chem, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Song, Chengwen,Wang, Tonghua,Qiu, Jieshan,et al. Effects of carbonization conditions on the properties of coal-based microfiltration carbon membranes[J]. JOURNAL OF POROUS MATERIALS,2008,15(1):1-6.
APA Song, Chengwen,Wang, Tonghua,Qiu, Jieshan,Cao, Yiming,&Cai, Tianxi.(2008).Effects of carbonization conditions on the properties of coal-based microfiltration carbon membranes.JOURNAL OF POROUS MATERIALS,15(1),1-6.
MLA Song, Chengwen,et al."Effects of carbonization conditions on the properties of coal-based microfiltration carbon membranes".JOURNAL OF POROUS MATERIALS 15.1(2008):1-6.
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