中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model
作者: Zheng, De-Sheng1;  Wang, Yuan1;  Liu, An-An1;  Wang, Hong-Fei1
关键词: interface ;  submonolayer ;  molecular orientation ;  second harmonic generation (SHG) ;  sum frequency generation vibrational spectroiscopy (SFG-VS) ;  Maxwell equations
刊名: INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY
发表日期: 2008
DOI: 10.1080/01442350802343981
卷: 27, 期:4, 页:629-664
收录类别: SCI
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The aim of this work is to present a coherent description of the microscopic theory of surface nonlinear optical spectroscopy for solving practical problems in understanding the details of the molecular interface. We review the related issues and show that by following microscopic molecular optics theory, second harmonic generation (SHG), as well as sum-frequency generation vibrational spectroscopy (SFG-VS), radiation from a monolayer or submonolayer can be rigorously treated as the radiation from an induced dipole lattice at the interface. In this approach, the introduction of an infinitesimally thin polarization sheet as in macroscopic theory with the Maxwell equations and the boundary conditions is no longer necessary. As a direct consequence, the ambiguity of the unaccounted dielectric constant of the interfacial layer is no longer an issue. Moreover, the anisotropic two-dimensional microscopic local field factors can be explicitly defined with the linear polarizability tensors of the interfacial molecules. Based on the planewise dipole sum rule in the molecular monolayer, experimental tests of this microscopic treatment with SHG and SFG-VS are discussed.
关键词[WOS]: 2ND HARMONIC-GENERATION ;  LANGMUIR-BLODGETT-FILMS ;  SELF-ASSEMBLED MONOLAYERS ;  REFLECTION INFRARED-SPECTROSCOPY ;  AROMATIC HYDROCARBON CRYSTALS ;  INTERFACIAL REFRACTIVE-INDEX ;  SFG VIBRATIONAL SPECTROSCOPY ;  X-RAY REFLECTIVITY ;  LOCAL-FIELD ;  LIQUID-CRYSTAL
语种: 英语
WOS记录号: WOS:000260163300002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141115
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Zheng, De-Sheng,Wang, Yuan,Liu, An-An,et al. Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,2008,27(4):629-664.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zheng, De-Sheng]'s Articles
 [Wang, Yuan]'s Articles
 [Liu, An-An]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zheng, De-Sheng]‘s Articles
 [Wang, Yuan]‘s Articles
 [Liu, An-An]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace