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Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model
Zheng, De-Sheng; Wang, Yuan; Liu, An-An; Wang, Hong-Fei
关键词Interface Submonolayer Molecular Orientation Second Harmonic Generation (Shg) Sum Frequency Generation Vibrational Spectroiscopy (Sfg-vs) Maxwell Equations
刊名INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY
2008
DOI10.1080/01442350802343981
27期:4页:629-664
收录类别SCI
文章类型Review
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]2ND HARMONIC-GENERATION ; LANGMUIR-BLODGETT-FILMS ; SELF-ASSEMBLED MONOLAYERS ; REFLECTION INFRARED-SPECTROSCOPY ; AROMATIC HYDROCARBON CRYSTALS ; INTERFACIAL REFRACTIVE-INDEX ; SFG VIBRATIONAL SPECTROSCOPY ; X-RAY REFLECTIVITY ; LOCAL-FIELD ; LIQUID-CRYSTAL
英文摘要The aim of this work is to present a coherent description of the microscopic theory of surface nonlinear optical spectroscopy for solving practical problems in understanding the details of the molecular interface. We review the related issues and show that by following microscopic molecular optics theory, second harmonic generation (SHG), as well as sum-frequency generation vibrational spectroscopy (SFG-VS), radiation from a monolayer or submonolayer can be rigorously treated as the radiation from an induced dipole lattice at the interface. In this approach, the introduction of an infinitesimally thin polarization sheet as in macroscopic theory with the Maxwell equations and the boundary conditions is no longer necessary. As a direct consequence, the ambiguity of the unaccounted dielectric constant of the interfacial layer is no longer an issue. Moreover, the anisotropic two-dimensional microscopic local field factors can be explicitly defined with the linear polarizability tensors of the interfacial molecules. Based on the planewise dipole sum rule in the molecular monolayer, experimental tests of this microscopic treatment with SHG and SFG-VS are discussed.
语种英语
WOS记录号WOS:000260163300002
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141115
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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GB/T 7714
Zheng, De-Sheng,Wang, Yuan,Liu, An-An,et al. Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model[J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,2008,27(4):629-664.
APA Zheng, De-Sheng,Wang, Yuan,Liu, An-An,&Wang, Hong-Fei.(2008).Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model.INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY,27(4),629-664.
MLA Zheng, De-Sheng,et al."Microscopic molecular optics theory of surface second harmonic generation and sum-frequency generation spectroscopy based on the discrete dipole lattice model".INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY 27.4(2008):629-664.
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