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题名: Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions
作者: Wang Xinliang1, 2;  Liang Xinmiao1
关键词: alcohol ;  selective oxidation ;  air ;  4-hydroxy-2,2,6,6-tetramethyl-piperidyl-1-oxy ;  ferric nitrate nonahydrate
刊名: CHINESE JOURNAL OF CATALYSIS
发表日期: 2008-09-01
卷: 29, 期:9, 页:935-939
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Engineering
英文摘要: A Fe(NO3)(3)/4-OH-TEMPO catalyst system was developed using the inexpensive organocatalyst 4-hydroxy-2,2,6,6-tetramethyl-piperidyl-1-oxy (4-OH-TEMPO) and the co-catalyst Fe(NO3)(3) center dot 9H(2)O. The catalytic molecular-oxygen-driven oxidation of a broad range of primary and secondary alcohols, which may contain carbon-carbon double bond, N, O, and S heteroatoms, to the corresponding aldehydes and ketones was investigated. The results showed that reaction is highly selective to the desired products when carried out at room temperature in ambient atmosphere air. The mechanism for the catalytic aerobic oxidation of alcohols by Fe (NO3)(3)/4-OH-TEMPO was discussed.
关键词[WOS]: TRANSITION-METAL-FREE ;  SELECTIVE OXIDATION ;  HIGHLY EFFICIENT ;  MOLECULAR-OXYGEN ;  TEMPO ;  ORGANOCATALYST ;  ALDEHYDES ;  MEDIATORS
语种: 英语
WOS记录号: WOS:000260196700019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141165
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Wang Xinliang,Liang Xinmiao. Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)(3)/4-OH-TEMPO under Mild Conditions[J]. CHINESE JOURNAL OF CATALYSIS,2008,29(9):935-939.
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