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Hydrogen storage capacity of nickel supported on a metal-organic framework compound under mild conditions
Liu Yingya1,2; Zhang Jian1,2; Zeng Julan1,2; Chu Hailiang1,2; Xu Fen1; Sun Lixian1
关键词Nickel Metal-organic Framework Compound Supported Composite Material Hydrogen Storage Capacity Impregnation Chemical Reduction Hydrogen Reduction
刊名CHINESE JOURNAL OF CATALYSIS
2008-07-01
29期:7页:655-659
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]HIGH H-2 ADSORPTION ; COORDINATION POLYMER ; SURFACE-AREA ; INCLUSION ; SPILLOVER ; BINDING ; MIL-101 ; SITES ; MOF ; ZN
英文摘要The traditional impregnation method was used to support nickel ions on the metal-organic framework compound MIL-101 (Cr(3)F(H(2)O)(2)O[(O(2)C)-C(6)H(4)-(CO(2))](3)center dot nH(2)O, n approximate to 5) for the preparation of a Ni/MIL-101 composite material. With two ways of impregnation (excessive impregnation and incipient wetness impregnation) followed by two ways of reduction (liquid chemical reduction and solid hydrogenation reduction), four Ni/MIL-101 samples were obtained. The hydrogen storage capacity of the Ni/MIL-101 samples was measured under mild conditions (25-100 degrees C, 0.01-4 MPa). Compared with the original MIL-101, Ni/MIL-101 had high hydrogen storage capacity because of the Ni particles supported on MIL-101. Among these samples, the sample prepared by excessive impregnation followed by liquid chemical reduction exhibited the highest hydrogen storage capacity of 1.02% at 100 degrees C and 4.0 MPa.
语种英语
WOS记录号WOS:000258484400014
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被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141190
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Liu Yingya,Zhang Jian,Zeng Julan,et al. Hydrogen storage capacity of nickel supported on a metal-organic framework compound under mild conditions[J]. CHINESE JOURNAL OF CATALYSIS,2008,29(7):655-659.
APA Liu Yingya,Zhang Jian,Zeng Julan,Chu Hailiang,Xu Fen,&Sun Lixian.(2008).Hydrogen storage capacity of nickel supported on a metal-organic framework compound under mild conditions.CHINESE JOURNAL OF CATALYSIS,29(7),655-659.
MLA Liu Yingya,et al."Hydrogen storage capacity of nickel supported on a metal-organic framework compound under mild conditions".CHINESE JOURNAL OF CATALYSIS 29.7(2008):655-659.
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