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题名: Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines
作者: Wang, Da-Wei1;  Wang, Xiao-Bing1;  Wang, Duo-Sheng1;  Lu, Sheng-Mei1;  Zhou, Yong-Gui1, 2;  Li, Yu-Xue2
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2009-04-03
DOI: 10.1021/jo900073z
卷: 74, 期:7, 页:2780-2787
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The enantioselective hydrogenation of 2-benzylquinolines and 2-functionalized and 2,3-disubstituted quinolines was developed by using the [Ir(COD)Cl]2/bisphosphine/I(2) system with up to 96% ee. Moreover, mechanistic studies revealed the hydrogenation mechanism of quinoline involves a 1,4-hydride addition, isomerization, and 1,2-hydride addition, and the catalytic active species may be a Ir(III) complex with chloride and iodide.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  N-IMINOPYRIDINIUM YLIDES ;  IR-F-BINAPHANE ;  HETEROAROMATIC-COMPOUNDS ;  HOMOGENEOUS HYDROGENATION ;  HANTZSCH ESTERS ;  COMPLEXES ;  LIGANDS ;  DERIVATIVES ;  INDOLES
语种: 英语
WOS记录号: WOS:000264627400018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141246
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Wang, Da-Wei,Wang, Xiao-Bing,Wang, Duo-Sheng,et al. Highly Enantioselective Iridium-Catalyzed Hydrogenation of 2-Benzylquinolines and 2-Functionalized and 2,3-Disubstituted Quinolines[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(7):2780-2787.
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