中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Selective formation of nitroanilines by selenium-catalyzed monoreduction of dinitrobenzenes with CO/H2O
作者: Liu, Xiao-zhi1;  Lu, Shi-wei2
关键词: CO ;  Monoreduction ;  Dinitrobenzenes ;  Selenium ;  Nitroanilines
刊名: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
发表日期: 2009-03-02
DOI: 10.1016/j.molcata.2008.10.014
卷: 300, 期:1-2, 页:36-40
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Nitroanilines are synthesized via selenium-catalyzed monoreduction of dinitrobenzenes with CO/H2O. The monoreduction occurs in high selectivity regardless of other reducible functionalities on the aromatic ring. This catalytic reaction is important from both synthetic and industrial points of view, because the reaction can be carried out with high yields of desired nitroanilines not only under high pressure but also under atmospheric pressure. There exists a phase-transfer process of the selenium catalyst in the reaction, which makes the catalyst easily separated from the reaction system by simple phase separation. (C) 2008 Elsevier B.V. All rights reserved.
关键词[WOS]: AROMATIC NITRO-COMPOUNDS ;  UTILIZING REDUCING ABILITY ;  CARBON-MONOXIDE ;  REDUCTION ;  AMINES ;  WATER ;  HYDROGENATION ;  TRIETHYLAMINE ;  NITROBENZENE ;  ACID
语种: 英语
WOS记录号: WOS:000264013400006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141256
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Liaoning Univ, Inst Rare & Scattered Met Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China

Recommended Citation:
Liu, Xiao-zhi,Lu, Shi-wei. Selective formation of nitroanilines by selenium-catalyzed monoreduction of dinitrobenzenes with CO/H2O[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,300(1-2):36-40.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Liu, Xiao-zhi]'s Articles
 [Lu, Shi-wei]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Liu, Xiao-zhi]‘s Articles
 [Lu, Shi-wei]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace