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题名: Asymmetric tandem Michael addition-ylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives
作者: Ye, Long-Wu1;  Wang, Shou-Bing2;  Wang, Qing-Gang1;  Sun, Xiu-Li1;  Tang, Yong1;  Zhou, Yong-Gui2
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2009
DOI: 10.1039/b900048h
期: 21, 页:3092-3094
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: The reaction of a crotonate-derived chiral phosphonium salt with alpha,beta-unsaturated carbonyl compounds in the presence of Cs(2)CO(3) affords optically active cyclohexa-1,3-diene derivatives with up to 90% ee in good yields.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE SYNTHESIS ;  CYCLOHEXADIENE DERIVATIVES ;  STEREOSELECTIVE-SYNTHESIS ;  WITTIG REACTION ;  HYDROGENATION ;  LIGANDS ;  INDUCTION ;  KETONES ;  VINYLCYCLOPROPANES ;  ATTRACTANTS
语种: 英语
WOS记录号: WOS:000266269700034
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141269
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Ye, Long-Wu,Wang, Shou-Bing,Wang, Qing-Gang,et al. Asymmetric tandem Michael addition-ylide olefination reaction for the synthesis of optically active cyclohexa-1,3-diene derivatives[J]. CHEMICAL COMMUNICATIONS,2009(21):3092-3094.
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