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Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA
Zheng, Xueli1,2; Xu, Weiliang3; Xiong, Zhitao1; Chua, Yongshen3; Wu, Guotao1; Qin, Song2; Chen, Hua2; Chen, Ping1
刊名JOURNAL OF MATERIALS CHEMISTRY
2009
DOI10.1039/b915851k
19期:44页:8426-8431
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Physical ; Materials Science, Multidisciplinary
研究领域[WOS]Chemistry ; Materials Science
关键词[WOS]N-H SYSTEM ; THERMAL-DECOMPOSITION ; COMPLEX HYDRIDES ; CHEMICAL-REACTION ; STORAGE MATERIALS ; AMMONIA-BORANE ; METAL-HYDRIDES ; LITHIUM ; LIB0.33N0.67H2.67 ; DEHYDROGENATION
英文摘要By adding a small amount of HMPA approximately 2.5 equivalent or ca. 8.1 wt% H-2 can be released from the LiAlH4-LiNH2 mixture at ambient temperature, which is similar to 370 degrees C lower than the corresponding solid-state dehydrogenation. NMR characterizations reveal the formation of intermediates, such as [AlH] and [AlN] species, during the dehydrogenation. LiNH2 induces the enrichment of [AlH] species in the liquid phase which further reacts with LiNH2 to produce H-2, Li2NH and Al.
语种英语
WOS记录号WOS:000271744600022
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被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141283
专题中国科学院大连化学物理研究所
作者单位1.Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Inst Homogeneous Catalysis, Chengdu 610064, Peoples R China
3.Natl Univ Singapore, Dept Chem, Fac Sci, Singapore 117543, Singapore
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GB/T 7714
Zheng, Xueli,Xu, Weiliang,Xiong, Zhitao,et al. Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA[J]. JOURNAL OF MATERIALS CHEMISTRY,2009,19(44):8426-8431.
APA Zheng, Xueli.,Xu, Weiliang.,Xiong, Zhitao.,Chua, Yongshen.,Wu, Guotao.,...&Chen, Ping.(2009).Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA.JOURNAL OF MATERIALS CHEMISTRY,19(44),8426-8431.
MLA Zheng, Xueli,et al."Ambient temperature hydrogen desorption from LiAlH4-LiNH2 mediated by HMPA".JOURNAL OF MATERIALS CHEMISTRY 19.44(2009):8426-8431.
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