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题名: Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
作者: Liu, Kun-hui1;  Yang, Chun-fan1;  Wang, Huan1;  Wu, Wei-qiang1;  Su, Hong-mei1
关键词: TR-FTIR ;  Dichloromethyl ;  NO2 ;  Reaction product channel
刊名: CHINESE JOURNAL OF CHEMICAL PHYSICS
发表日期: 2009-04-01
DOI: 10.1088/1674-0068/22/02/134-138
卷: 22, 期:2, 页:134-138
收录类别: SCI ;  ISTP
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: The environmentally important free radical reaction of chlorinated methyl CHCl2 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Vibrationally excited products of CHClO, NO, CO, and HCl are observed in the high-resolution IR emission spectra and three possible reaction channels are therefore elucidated. In particular, the product CO is newly detected and the product HCl is identified explicitly as a yield from the CHCl2+NO2 reaction, taking advantage of the sensitive detection of HCl and CO with TR-FTIR. These results are of particular interests to understand the related realistic chemical processes including atmospheric photochemistry, biofuel combustion, waste destruction, and smoking fire.
关键词[WOS]: RADICAL-MOLECULE REACTION ;  DIODE-LASER ;  KINETICS ;  CL ;  PHOTODISSOCIATION ;  SPECTROSCOPY ;  TEMPERATURE ;  CHEMISTRY ;  MECHANISM ;  CH2BRCL
语种: 英语
WOS记录号: WOS:000265896000006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141296
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China

Recommended Citation:
Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,et al. Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2009,22(2):134-138.
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