DICP OpenIR
Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2
Liu, Kun-hui; Yang, Chun-fan; Wang, Huan; Wu, Wei-qiang; Su, Hong-mei
关键词Tr-ftir Dichloromethyl No2 Reaction Product Channel
刊名CHINESE JOURNAL OF CHEMICAL PHYSICS
2009-04-01
DOI10.1088/1674-0068/22/02/134-138
22期:2页:134-138
收录类别SCI ; ISTP
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]RADICAL-MOLECULE REACTION ; DIODE-LASER ; KINETICS ; CL ; PHOTODISSOCIATION ; SPECTROSCOPY ; TEMPERATURE ; CHEMISTRY ; MECHANISM ; CH2BRCL
英文摘要The environmentally important free radical reaction of chlorinated methyl CHCl2 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Vibrationally excited products of CHClO, NO, CO, and HCl are observed in the high-resolution IR emission spectra and three possible reaction channels are therefore elucidated. In particular, the product CO is newly detected and the product HCl is identified explicitly as a yield from the CHCl2+NO2 reaction, taking advantage of the sensitive detection of HCl and CO with TR-FTIR. These results are of particular interests to understand the related realistic chemical processes including atmospheric photochemistry, biofuel combustion, waste destruction, and smoking fire.
语种英语
WOS记录号WOS:000265896000006
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141296
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China
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Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,et al. Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2009,22(2):134-138.
APA Liu, Kun-hui,Yang, Chun-fan,Wang, Huan,Wu, Wei-qiang,&Su, Hong-mei.(2009).Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2.CHINESE JOURNAL OF CHEMICAL PHYSICS,22(2),134-138.
MLA Liu, Kun-hui,et al."Time-Resolved FTIR Study on the Reaction of CHCl2 with NO2".CHINESE JOURNAL OF CHEMICAL PHYSICS 22.2(2009):134-138.
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