DICP OpenIR
Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O
Liu Beiping3; Tan Zhicheng1,2; Zhang Jingnan1,2; Lue Xuechuan4; Zhang Dashun3; Chen Zhengan3
KeywordTb(Gly)(2)Cl-3 Center Dot 3h(2)o Heat Capacity Standard Molar Enthalpy Ir Spectra Tg-dtg Analysis
Source PublicationCHINESE JOURNAL OF CHEMISTRY
2009-07-01
Volume27Issue:7Pages:1244-1248
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordHEAT-CAPACITY MEASUREMENTS ; ADIABATIC CALORIMETER ; SMALL SAMPLES ; ACID
AbstractA terbium complex with glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O was synthesized and its IR spectrum was determined. The heat capacity of the complex was measured with a high-precision automatic adiabatic calorimeter over the temperature range from 81 to 378 K. From 170 to 247 K, two solid-solid phase transitions occurred at 186.054 and 244.063 K, respectively. Thermal decomposition of the complex was studied by thermogravimetric (TG) techniques and a possible mechanism for the decomposition was suggested. By isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of Tb(Gly)(2)Cl-3 center dot 3H(2)O was derived to be -(3109.5 +/- 3.1) kJ.mol(-1).
Language英语
WOS IDWOS:000268625200006
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141299
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China
3.Hunan Univ Arts & Sci, Dept Chem, Changde 415000, Hunan, Peoples R China
4.Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Liu Beiping,Tan Zhicheng,Zhang Jingnan,et al. Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O[J]. CHINESE JOURNAL OF CHEMISTRY,2009,27(7):1244-1248.
APA Liu Beiping,Tan Zhicheng,Zhang Jingnan,Lue Xuechuan,Zhang Dashun,&Chen Zhengan.(2009).Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O.CHINESE JOURNAL OF CHEMISTRY,27(7),1244-1248.
MLA Liu Beiping,et al."Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O".CHINESE JOURNAL OF CHEMISTRY 27.7(2009):1244-1248.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu Beiping]'s Articles
[Tan Zhicheng]'s Articles
[Zhang Jingnan]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu Beiping]'s Articles
[Tan Zhicheng]'s Articles
[Zhang Jingnan]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu Beiping]'s Articles
[Tan Zhicheng]'s Articles
[Zhang Jingnan]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.