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Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O
Liu Beiping3; Tan Zhicheng1,2; Zhang Jingnan1,2; Lue Xuechuan4; Zhang Dashun3; Chen Zhengan3
关键词Tb(Gly)(2)Cl-3 Center Dot 3h(2)o Heat Capacity Standard Molar Enthalpy Ir Spectra Tg-dtg Analysis
刊名CHINESE JOURNAL OF CHEMISTRY
2009-07-01
27期:7页:1244-1248
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]HEAT-CAPACITY MEASUREMENTS ; ADIABATIC CALORIMETER ; SMALL SAMPLES ; ACID
英文摘要A terbium complex with glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O was synthesized and its IR spectrum was determined. The heat capacity of the complex was measured with a high-precision automatic adiabatic calorimeter over the temperature range from 81 to 378 K. From 170 to 247 K, two solid-solid phase transitions occurred at 186.054 and 244.063 K, respectively. Thermal decomposition of the complex was studied by thermogravimetric (TG) techniques and a possible mechanism for the decomposition was suggested. By isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of Tb(Gly)(2)Cl-3 center dot 3H(2)O was derived to be -(3109.5 +/- 3.1) kJ.mol(-1).
语种英语
WOS记录号WOS:000268625200006
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141299
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China
3.Hunan Univ Arts & Sci, Dept Chem, Changde 415000, Hunan, Peoples R China
4.Shihua Univ, Sch Chem & Mat Sci, Fushun 113001, Liaoning, Peoples R China
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GB/T 7714
Liu Beiping,Tan Zhicheng,Zhang Jingnan,et al. Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O[J]. CHINESE JOURNAL OF CHEMISTRY,2009,27(7):1244-1248.
APA Liu Beiping,Tan Zhicheng,Zhang Jingnan,Lue Xuechuan,Zhang Dashun,&Chen Zhengan.(2009).Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O.CHINESE JOURNAL OF CHEMISTRY,27(7),1244-1248.
MLA Liu Beiping,et al."Thermodynamic Study on Complex of Terbium with Glycine Tb(Gly)(2)Cl-3 center dot 3H(2)O".CHINESE JOURNAL OF CHEMISTRY 27.7(2009):1244-1248.
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