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In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene
Yan, Li1; Ding, Yun J.1,2; Lin, Li W.1,2; Zhu, He J.1; Yin, Hong M.1; Li, Xian M.1; Lu, Yuan1
关键词Triphenyl Phosphine Rh Sba-15 Hydroformylation Propene
刊名JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2009-03-02
DOI10.1016/j.molcata.2008.10.050
300期:1-2页:116-120
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]FIXED-BED HYDROFORMYLATION ; HOMOGENEOUS CATALYSIS ; RHODIUM ; LIGAND ; PRECURSORS ; SILICA
英文摘要A method of in situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of heterogeneous Rh/SBA-15 catalyst has been developed and confirmed in this work. The amount of active species formed inside the pores can be controlled by the support pore size. This class of PPh3-Rh/SBA-15 catalyst has been employed in propene hydroformylation to be highly active, selective, stable, easily workable and recyclable. Using TEM, solid-state (31)p MAS NMR, and in situ FT-IR, HRh(CO)(2)(PPh3)(2) active species can be characterized. (C) 2008 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000264013400017
引用统计
被引频次:17[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141324
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
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GB/T 7714
Yan, Li,Ding, Yun J.,Lin, Li W.,et al. In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,300(1-2):116-120.
APA Yan, Li.,Ding, Yun J..,Lin, Li W..,Zhu, He J..,Yin, Hong M..,...&Lu, Yuan.(2009).In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,300(1-2),116-120.
MLA Yan, Li,et al."In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 300.1-2(2009):116-120.
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