DICP OpenIR
In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene
Yan, Li1; Ding, Yun J.1,2; Lin, Li W.1,2; Zhu, He J.1; Yin, Hong M.1; Li, Xian M.1; Lu, Yuan1
KeywordTriphenyl Phosphine Rh Sba-15 Hydroformylation Propene
Source PublicationJOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
2009-03-02
DOI10.1016/j.molcata.2008.10.050
Volume300Issue:1-2Pages:116-120
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordFIXED-BED HYDROFORMYLATION ; HOMOGENEOUS CATALYSIS ; RHODIUM ; LIGAND ; PRECURSORS ; SILICA
AbstractA method of in situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of heterogeneous Rh/SBA-15 catalyst has been developed and confirmed in this work. The amount of active species formed inside the pores can be controlled by the support pore size. This class of PPh3-Rh/SBA-15 catalyst has been employed in propene hydroformylation to be highly active, selective, stable, easily workable and recyclable. Using TEM, solid-state (31)p MAS NMR, and in situ FT-IR, HRh(CO)(2)(PPh3)(2) active species can be characterized. (C) 2008 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000264013400017
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141324
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Appl Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Yan, Li,Ding, Yun J.,Lin, Li W.,et al. In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2009,300(1-2):116-120.
APA Yan, Li.,Ding, Yun J..,Lin, Li W..,Zhu, He J..,Yin, Hong M..,...&Lu, Yuan.(2009).In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,300(1-2),116-120.
MLA Yan, Li,et al."In situ formation of HRh(CO)(2)(PPh3)(2) active species on the surface of a SBA-15 supported heterogeneous catalyst and the effect of support pore size on the hydroformylation of propene".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 300.1-2(2009):116-120.
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