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Palladium-Catalyzed Carbonylative Cycloisomerization of gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans
Li, Yu1; Yu, Zhengkun1,2
刊名JOURNAL OF ORGANIC CHEMISTRY
2009-11-20
DOI10.1021/jo9020634
74期:22页:8904-8907
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]HIGHLY SUBSTITUTED FURANS ; TETRASUBSTITUTED FURANS ; COUPLING REACTION ; 1,3-DIKETONES ; KETONES ; ALKYNES ; DERIVATIVES ; ANNULATION ; ALCOHOLS ; SYSTEMS
英文摘要Di- and trisubstituted furan derivatives have been efficiently synthesized via palladium(II)-catalyzed intramolecular carbonylative cycloisomerization of gamma-propynyl-1,3-diketones with aryl iodides and carbon monoxide. The mechanism suggests that in situ generated acylpalladium species from the carbonylation of aryl iodide initiates the reaction followed by cyclization of the enolized isomer of a 1,3-diketone substrate via carbon-carbon triple bond activation.
语种英语
WOS记录号WOS:000271662500064
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141339
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
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GB/T 7714
Li, Yu,Yu, Zhengkun. Palladium-Catalyzed Carbonylative Cycloisomerization of gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(22):8904-8907.
APA Li, Yu,&Yu, Zhengkun.(2009).Palladium-Catalyzed Carbonylative Cycloisomerization of gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans.JOURNAL OF ORGANIC CHEMISTRY,74(22),8904-8907.
MLA Li, Yu,et al."Palladium-Catalyzed Carbonylative Cycloisomerization of gamma-Propynyl-1,3-diketones: A Concise Route to Polysubstituted Furans".JOURNAL OF ORGANIC CHEMISTRY 74.22(2009):8904-8907.
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