DICP OpenIR
CONTRIBUTION OF THE REPULSIVE INTERACTION BETWEEN FRAGMENTS TO ROTATIONAL DISTRIBUTION OF THE FRAGMENTS IN PHOTOLYSIS
Lue Richang
刊名ACTA PHYSICO-CHIMICA SINICA
1985
DOI10.3866/PKU.WHXB19850608
1期:6页:547-555
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要Many studies on rotational distribution of photofragments have been done both in experimental and in theoretical aspects during the past decade, but comparisions of the theoretical results with the experimental ones remain few and far between. An attempt has been made to emphasize the effects of the repulsive interaction between photofragments on their rotational distribution. A simple classical model was postulated and the interpretation with this model is qualitatively in good ag reement with a series of experimental observations listed in Table 1. Based on this model, the angular momentum of the photofragments could be divided into two parts, one from the rotation of the parent molecule, the other produced during the sepa ration, i. e, by the repulsive interaction. The cooling of the parent molecules in a supersonic jet could only affect the first part. The second part depends mainly upon the nature of the dissociative potential surface. Using this simple model, one can also obtain some dynamic informations including some characteristics of the potential surface. A number of examples are given in the discussion, which show that the interpretation with this model is fairly consistent with the results observed in the photolysis of CICN, BrCN, C2N2 C4N2 etc. in effusive or super sonic molecular beams. This qualitative agreement means that the classical model is helpful if the quantum theory on the rotational distribution of photofragraents is not available in practice
语种英语
WOS记录号WOS:000207568200008
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141358
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Beijing 100864, Peoples R China
推荐引用方式
GB/T 7714
Lue Richang. CONTRIBUTION OF THE REPULSIVE INTERACTION BETWEEN FRAGMENTS TO ROTATIONAL DISTRIBUTION OF THE FRAGMENTS IN PHOTOLYSIS[J]. ACTA PHYSICO-CHIMICA SINICA,1985,1(6):547-555.
APA Lue Richang.(1985).CONTRIBUTION OF THE REPULSIVE INTERACTION BETWEEN FRAGMENTS TO ROTATIONAL DISTRIBUTION OF THE FRAGMENTS IN PHOTOLYSIS.ACTA PHYSICO-CHIMICA SINICA,1(6),547-555.
MLA Lue Richang."CONTRIBUTION OF THE REPULSIVE INTERACTION BETWEEN FRAGMENTS TO ROTATIONAL DISTRIBUTION OF THE FRAGMENTS IN PHOTOLYSIS".ACTA PHYSICO-CHIMICA SINICA 1.6(1985):547-555.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Lue Richang]的文章
百度学术
百度学术中相似的文章
[Lue Richang]的文章
必应学术
必应学术中相似的文章
[Lue Richang]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。