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Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)
Di, You-Ying1; Hong, Yuan-Ping1; Kong, Yu-Xia1; Yang, Wei-Wei1; Tan, Zhi-Cheng2
关键词Zn(Nic)(2)Center Dot h(2)o(s) Solid Phase Reaction Isoperibol Solution-reaction Calorimetry Standard Molar Enthalpy Of Dissolution Standard Molar Enthalpy Of Formation
刊名JOURNAL OF CHEMICAL THERMODYNAMICS
2009
DOI10.1016/j.jct.2008.07.015
41期:1页:80-83
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Thermodynamics ; Chemistry, Physical
研究领域[WOS]Thermodynamics ; Chemistry
关键词[WOS]ENTHALPIES
英文摘要A novel compound, viz. zinc nicotinate monohydrate, was synthesized by the method of room temperature solid phase synthesis. The techniques of FT-IR chemical and elemental analyses and X-ray powder diffraction were applied to characterise the structure and composition of the complex. In accordance with Hess' law, a thermochemical cycle was designed and the enthalpy change of the solid phase reaction of nicotinic acid with hydrated zinc acetate was determined to be Delta(r)H(m)(o) = (46.71 +/- 0.21) kJ . mol(-1) by use of an isoperibol solution-reaction calorimeter. The standard molar enthalpy of formation of the title complex Zn(NiC)(2) . H(2)O(s) was calculated as -(1062.3 +/- 2.0) kJ . mol(-1) by use of the enthalpies of dissolution and other auxiliary thermodynamic data. (C) 2008 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000262195600014
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141363
专题中国科学院大连化学物理研究所
作者单位1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
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GB/T 7714
Di, You-Ying,Hong, Yuan-Ping,Kong, Yu-Xia,et al. Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2009,41(1):80-83.
APA Di, You-Ying,Hong, Yuan-Ping,Kong, Yu-Xia,Yang, Wei-Wei,&Tan, Zhi-Cheng.(2009).Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid).JOURNAL OF CHEMICAL THERMODYNAMICS,41(1),80-83.
MLA Di, You-Ying,et al."Synthesis, characterization, and thermochemistry of the solid state coordination compound Zn(Nic)(2) center dot H(2)O(s) (Nic = nicotinic acid)".JOURNAL OF CHEMICAL THERMODYNAMICS 41.1(2009):80-83.
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