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题名: An expeditious and high-yield formal synthesis of hirsutene using Rh(I)-catalyzed [(5+2)+1] cycloaddition
作者: Fan, Xiaohui1, 2, 3;  Tang, Min-Xian1;  Zhuo, Lian-Gang1;  Tu, Yong Qiang2, 3;  Yu, Zhi-Xiang1
刊名: TETRAHEDRON LETTERS
发表日期: 2009-01-14
DOI: 10.1016/j.tetlet.2008.10.023
卷: 50, 期:2, 页:155-157
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An expeditious and high-yield formal synthesis of hirsutene has been achieved. This synthesis features Rh(I)-catalyzed [(5+2)+1] cycloaddition to construct a bicyclic cyclooctenone, which can be efficiently transformed to bicyclic diketone, an advanced intermediate for racemic and asymmetric syntheses of hirsutene. (C) 2008 Elsevier Ltd. All rights reserved.
关键词[WOS]: ASYMMETRIC-SYNTHESIS ;  NATURAL-PRODUCTS ;  IDEAL SYNTHESIS ;  (+/-)-HIRSUTENE ;  DESYMMETRIZATION ;  (-)-HIRSUTENE ;  REARRANGEMENT
语种: 英语
WOS记录号: WOS:000263218700004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141366
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
3.Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

Recommended Citation:
Fan, Xiaohui,Tang, Min-Xian,Zhuo, Lian-Gang,et al. An expeditious and high-yield formal synthesis of hirsutene using Rh(I)-catalyzed [(5+2)+1] cycloaddition[J]. TETRAHEDRON LETTERS,2009,50(2):155-157.
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