DICP OpenIR
Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)
Cao, Lei1,2; Ni, Changjun1; Yuan, Zhongshan1; Wang, Shudong1
关键词Autothermal Reforming Methane Ceo2-zro2 Rare-earth
刊名CATALYSIS COMMUNICATIONS
2009-03-30
DOI10.1016/j.catcom.2009.01.015
10期:8页:1192-1195
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]CEO2-ZRO2 SOLID-SOLUTIONS ; HYDROGEN-PRODUCTION ; MIXED OXIDES ; STRUCTURAL-PROPERTIES ; SYNGAS ; OXIDATION ; RH ; PERFORMANCE ; BEHAVIOR ; SUPPORT
英文摘要Trivalent rare-earth (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)-doped Ce0.45Zr0.45RE0.1 solid solutions were synthesized via reverse micro-emulsion method and the catalytic performance of the Rh-supported catalysts was investigated in autothermal reforming of methane (ATR). It was found that CH4 conversion went through a maximum as a function of oxygen storage capacity (OSC) value of the support. Higher OSC will help to enhance the reactivity toward water-gas-shift (WGS) reaction, resulting higher H-2/CO ratio. A striking correlation between OSC and H-2/CO ratio was observed, which presented a maximum for the Rh/CZLa (3.4) and a minimum for the Rh/CZTb (2.6) catalysts. (C) 2009 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000264975200014
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141375
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Cao, Lei,Ni, Changjun,Yuan, Zhongshan,et al. Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)[J]. CATALYSIS COMMUNICATIONS,2009,10(8):1192-1195.
APA Cao, Lei,Ni, Changjun,Yuan, Zhongshan,&Wang, Shudong.(2009).Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb).CATALYSIS COMMUNICATIONS,10(8),1192-1195.
MLA Cao, Lei,et al."Correlation between catalytic selectivity and oxygen storage capacity in autothermal reforming of methane over Rh/Ce0.45Zr0.45RE0.1 catalysts (RE = La, Pr, Nd, Sm, Eu, Gd, Tb)".CATALYSIS COMMUNICATIONS 10.8(2009):1192-1195.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Cao, Lei]的文章
[Ni, Changjun]的文章
[Yuan, Zhongshan]的文章
百度学术
百度学术中相似的文章
[Cao, Lei]的文章
[Ni, Changjun]的文章
[Yuan, Zhongshan]的文章
必应学术
必应学术中相似的文章
[Cao, Lei]的文章
[Ni, Changjun]的文章
[Yuan, Zhongshan]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。