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题名: VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl
作者: Li Hongzhi1;  Wang Xuebin1;  Kong Fanao1;  Zhu Qihe1
关键词: Intramolecular energy transfer ;  IR emission spectroscopy ;  Heavy atom effect ;  Chlorotrimethylsilane
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1993
DOI: 10.3866/PKU.WHXB19930404
卷: 9, 期:4, 页:447-449
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The vibrationally excited OH(v) from the reaction of O(D-1)+Si(CH3)(3)Cl was observed by UV lasre photolysis/FTIR emission spectroscopy. The vibrational number was only up to 3 with a ratio of 1:0.3:0 1 for v=1:2:3. Comparing this result with the similar reaction of O(D-1) + Si(CH3)(4) which OH(v) vibrational number was high up to 4 with a ration of 1:1:1:0:3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of Cl for CH3 affected the extent of heavy Si atom blooking the energy migratio in a molecule. This results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer.
语种: 英语
WOS记录号: WOS:000207577600004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141380
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Li Hongzhi,Wang Xuebin,Kong Fanao,et al. VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl[J]. ACTA PHYSICO-CHIMICA SINICA,1993,9(4):447-449.
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