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VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl
Li Hongzhi; Wang Xuebin; Kong Fanao; Zhu Qihe
关键词Intramolecular Energy Transfer Ir Emission Spectroscopy Heavy Atom Effect Chlorotrimethylsilane
刊名ACTA PHYSICO-CHIMICA SINICA
1993
DOI10.3866/PKU.WHXB19930404
9期:4页:447-449
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The vibrationally excited OH(v) from the reaction of O(D-1)+Si(CH3)(3)Cl was observed by UV lasre photolysis/FTIR emission spectroscopy. The vibrational number was only up to 3 with a ratio of 1:0.3:0 1 for v=1:2:3. Comparing this result with the similar reaction of O(D-1) + Si(CH3)(4) which OH(v) vibrational number was high up to 4 with a ration of 1:1:1:0:3 for v=1:2:3:4 under the same experimental conditions, it was found that the substitution of Cl for CH3 affected the extent of heavy Si atom blooking the energy migratio in a molecule. This results identifies the prediction that the characteristic of electrons in central atom plays an important role in intramolecular energy transfer.
语种英语
WOS记录号WOS:000207577600004
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141380
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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GB/T 7714
Li Hongzhi,Wang Xuebin,Kong Fanao,et al. VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl[J]. ACTA PHYSICO-CHIMICA SINICA,1993,9(4):447-449.
APA Li Hongzhi,Wang Xuebin,Kong Fanao,&Zhu Qihe.(1993).VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl.ACTA PHYSICO-CHIMICA SINICA,9(4),447-449.
MLA Li Hongzhi,et al."VIBRATIONAL EXCITATION OF OH(v <= 3) FROM THE REACTION OF O(D-1) + Si(CH3)(3)Cl".ACTA PHYSICO-CHIMICA SINICA 9.4(1993):447-449.
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