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Microwave-Assisted Preparation and Hydrazine Decomposition Properties of Nanostructured Tungsten Carbides on Carbon Nanotubes
Liang, Changhai1; Ding, Ling1; Wang, Aiqin2; Ma, Zhiqiang1; Qiu, Jieshan1; Zhang, Tao2
刊名INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
2009-03-18
DOI10.1021/ie801591x
48期:6页:3244-3248
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology
类目[WOS]Engineering, Chemical
研究领域[WOS]Engineering
关键词[WOS]TRANSITION-METAL CARBIDES ; SUPPORTED MOLYBDENUM CARBIDE ; CHEMICAL-VAPOR-DEPOSITION ; SURFACE-AREA ; CATALYTIC PROPERTIES ; HYDROGENATION ; REDUCTION ; NITRIDES ; OXYGEN ; MO2C
英文摘要Nearly monodispersed nanostructured tungsten carbide particles on carbon nanotubes (CNTs) have successfully been synthesized by microwave-assisted metal-organic chemical vapor deposition (MOCVD) at atmospheric pressure in a fluidized bed reactor. The results show that the tungsten carbide particles with 2-5 nm on CNTs can be formed several minutes and the particle sizes increase with the increase of microwave irradiation time. The preoxidation of CNTs is not necessary in the microwave-assisted MOCVD. The resulting materials are active catalysts for hydrazine decomposition and exhibit high selectivity to hydrogen, indicating that nanostructured tungsten carbides on CNTs is an inexpensive and promising alternative to the noble-metal catalysts for hydrazine decomposition. The microwave-assisted MOCVD is of great potential in the controlled synthesis of supported catalytic materials.
语种英语
WOS记录号WOS:000264221600054
引用统计
被引频次:21[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141408
专题中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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GB/T 7714
Liang, Changhai,Ding, Ling,Wang, Aiqin,et al. Microwave-Assisted Preparation and Hydrazine Decomposition Properties of Nanostructured Tungsten Carbides on Carbon Nanotubes[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2009,48(6):3244-3248.
APA Liang, Changhai,Ding, Ling,Wang, Aiqin,Ma, Zhiqiang,Qiu, Jieshan,&Zhang, Tao.(2009).Microwave-Assisted Preparation and Hydrazine Decomposition Properties of Nanostructured Tungsten Carbides on Carbon Nanotubes.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,48(6),3244-3248.
MLA Liang, Changhai,et al."Microwave-Assisted Preparation and Hydrazine Decomposition Properties of Nanostructured Tungsten Carbides on Carbon Nanotubes".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 48.6(2009):3244-3248.
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