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Preparation of Sulphonated Zirconium Phosphate-Phenylphosphonates and Their Catalytic Properties in Carbonylation of Formaldehyde
Sun Ying1,2; Zhang Yangyang1; Qi Yue1; Wang Hua1; Liu Hongchao1; Shen Jianghan1; Liu Zhongmin1
KeywordZirconium Phenyl Phosphonate Sulfonation Formaldehyde Carbonylation Methyl Glycolate
Source PublicationCHINESE JOURNAL OF CATALYSIS
2009-08-01
Volume30Issue:8Pages:786-790
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordEXCHANGE RESIN CATALYSTS ; METHYL METHOXY ACETATE ; FORMATE ; PHOSPHONATES ; GLYCOLATE ; SULFOPHOSPHONATES ; HETEROPOLYACIDS ; CONDENSATION ; CHEMISTRY ; AMINE
AbstractZirconium phenyl phosphonate Zr(C(6)H(5)PO(3))(2)center dot nH(2)O and its derivatives Zr(C(6)H(5)PO(3))(2)center dot(HPO(4))(x)center dot nH(2)O and Zr(C(6)H(5)PO(3))(2-x)(HPO(3))(x)center dot nH(2)O were synthesized and sulphonated. The pre- and post-sulfonation samples were characterized by inductively coupled plasma, X-ray diffraction, thermogravimetry, and infrared spectroscopy. The samples are all typical layered crystal with different interlayer spacings. Zirconium phosphate sulfophenylphosphonates (SZrPP-n) possessed high acidity amount and thermal stability. SZrPP-n was found to be an efficient and stable solid acid catalyst for carbonylation of formaldehyde.
Language英语
WOS IDWOS:000270149200012
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141421
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Sun Ying,Zhang Yangyang,Qi Yue,et al. Preparation of Sulphonated Zirconium Phosphate-Phenylphosphonates and Their Catalytic Properties in Carbonylation of Formaldehyde[J]. CHINESE JOURNAL OF CATALYSIS,2009,30(8):786-790.
APA Sun Ying.,Zhang Yangyang.,Qi Yue.,Wang Hua.,Liu Hongchao.,...&Liu Zhongmin.(2009).Preparation of Sulphonated Zirconium Phosphate-Phenylphosphonates and Their Catalytic Properties in Carbonylation of Formaldehyde.CHINESE JOURNAL OF CATALYSIS,30(8),786-790.
MLA Sun Ying,et al."Preparation of Sulphonated Zirconium Phosphate-Phenylphosphonates and Their Catalytic Properties in Carbonylation of Formaldehyde".CHINESE JOURNAL OF CATALYSIS 30.8(2009):786-790.
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