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New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition
Zou, Dong-Yun1; Duan, Zheng-Chao2; Hu, Xiang-Ping1,2; Zheng, Zhuo2
刊名TETRAHEDRON-ASYMMETRY
2009-02-12
DOI10.1016/j.tetasy.2009.01.013
20期:2页:235-239
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC CONJUGATE ADDITION ; FERROCENYLPHOSPHINE-AMIDINE LIGANDS ; N-H PROTON ; DIALKYLZINC REAGENTS ; ALLYLIC ALKYLATION ; CYCLIC ENONES ; ORGANOMETALLIC REAGENTS ; ACYCLIC NITROALKENES ; ORGANOZINC REAGENTS ; ACID-DERIVATIVES
英文摘要A new family of chiral bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands has been prepared and successfully applied in the Cu-catalyzed asymmetric 1,4-conjugate addition of diethylzinc to a variety Of Of,P-Unsaturated compounds, in which up to 99% ee was obtained for nitroalkenes at -78 degrees C and >98% ee for cyclohexenone at -30 degrees C, comparable to or higher than those obtained with the most efficient monophosphoramidite ligands reported so far. (C) 2009 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000264648900014
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141424
专题中国科学院大连化学物理研究所
作者单位1.China Agr Univ, Beijing 100094, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zou, Dong-Yun,Duan, Zheng-Chao,Hu, Xiang-Ping,et al. New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition[J]. TETRAHEDRON-ASYMMETRY,2009,20(2):235-239.
APA Zou, Dong-Yun,Duan, Zheng-Chao,Hu, Xiang-Ping,&Zheng, Zhuo.(2009).New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition.TETRAHEDRON-ASYMMETRY,20(2),235-239.
MLA Zou, Dong-Yun,et al."New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition".TETRAHEDRON-ASYMMETRY 20.2(2009):235-239.
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