DICP OpenIR
New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition
Zou, Dong-Yun1; Duan, Zheng-Chao2; Hu, Xiang-Ping1,2; Zheng, Zhuo2
Source PublicationTETRAHEDRON-ASYMMETRY
2009-02-12
DOI10.1016/j.tetasy.2009.01.013
Volume20Issue:2Pages:235-239
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Inorganic & Nuclear ; Chemistry, Organic ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordASYMMETRIC CONJUGATE ADDITION ; FERROCENYLPHOSPHINE-AMIDINE LIGANDS ; N-H PROTON ; DIALKYLZINC REAGENTS ; ALLYLIC ALKYLATION ; CYCLIC ENONES ; ORGANOMETALLIC REAGENTS ; ACYCLIC NITROALKENES ; ORGANOZINC REAGENTS ; ACID-DERIVATIVES
AbstractA new family of chiral bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands has been prepared and successfully applied in the Cu-catalyzed asymmetric 1,4-conjugate addition of diethylzinc to a variety Of Of,P-Unsaturated compounds, in which up to 99% ee was obtained for nitroalkenes at -78 degrees C and >98% ee for cyclohexenone at -30 degrees C, comparable to or higher than those obtained with the most efficient monophosphoramidite ligands reported so far. (C) 2009 Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000264648900014
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141424
Collection中国科学院大连化学物理研究所
Affiliation1.China Agr Univ, Beijing 100094, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Zou, Dong-Yun,Duan, Zheng-Chao,Hu, Xiang-Ping,et al. New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition[J]. TETRAHEDRON-ASYMMETRY,2009,20(2):235-239.
APA Zou, Dong-Yun,Duan, Zheng-Chao,Hu, Xiang-Ping,&Zheng, Zhuo.(2009).New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition.TETRAHEDRON-ASYMMETRY,20(2),235-239.
MLA Zou, Dong-Yun,et al."New bis(1-ferrocenylethyl)amine-derived monodentate phosphoramidite ligands for highly enantioselective copper-catalyzed 1,4-conjugate addition".TETRAHEDRON-ASYMMETRY 20.2(2009):235-239.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zou, Dong-Yun]'s Articles
[Duan, Zheng-Chao]'s Articles
[Hu, Xiang-Ping]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zou, Dong-Yun]'s Articles
[Duan, Zheng-Chao]'s Articles
[Hu, Xiang-Ping]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zou, Dong-Yun]'s Articles
[Duan, Zheng-Chao]'s Articles
[Hu, Xiang-Ping]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.