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1-Lithio-1,3-dienes as useful building blocks in organic synthesis
Zhang, Wen-Xiong; Xi, Zhenfeng
关键词Organolithium Reagents Carbonyllithium Lithio-1 Carbolithiation 3-butadienes Lithioketimines
刊名PURE AND APPLIED CHEMISTRY
2009-02-01
DOI10.1351/PAC-CON-08-08-04
81期:2页:235-246
收录类别SCI ; ISTP
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]FISCHER CARBENE COMPLEXES ; DEAROMATIZING ANIONIC CYCLIZATION ; TRANSITION-METAL-COMPLEXES ; EFFICIENT SYNTHESIS ; CARBON-MONOXIDE ; CYCLOPENTADIENE DERIVATIVES ; ELECTROPHILIC CYCLIZATION ; STEREOSELECTIVE-SYNTHESIS ; SKELETAL REARRANGEMENT ; BENZOPYRANYLIDENETUNGSTEN(0) COMPLEXES
英文摘要Both intermolecular reactivities toward C-O and C-N unsaturated substrates and intramolecular reactions of various 1-lithio-1,3-dienes are briefly summarized. Results reveal that intramolecular synergy between the alkenyllithium moiety and the butadienyl skeleton make 1-lithio-1,3-diene derivatives useful and unique as building blocks in organic synthesis. It is demonstrated that substitution patterns and the nature of the substituents on the butadienyl skeleton have remarkable effects on reaction pathways.
语种英语
WOS记录号WOS:000263531100007
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141465
专题中国科学院大连化学物理研究所
作者单位Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
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Zhang, Wen-Xiong,Xi, Zhenfeng. 1-Lithio-1,3-dienes as useful building blocks in organic synthesis[J]. PURE AND APPLIED CHEMISTRY,2009,81(2):235-246.
APA Zhang, Wen-Xiong,&Xi, Zhenfeng.(2009).1-Lithio-1,3-dienes as useful building blocks in organic synthesis.PURE AND APPLIED CHEMISTRY,81(2),235-246.
MLA Zhang, Wen-Xiong,et al."1-Lithio-1,3-dienes as useful building blocks in organic synthesis".PURE AND APPLIED CHEMISTRY 81.2(2009):235-246.
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