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题名: 1-Lithio-1,3-dienes as useful building blocks in organic synthesis
作者: Zhang, Wen-Xiong1;  Xi, Zhenfeng1
关键词: organolithium reagents ;  lithio-1,3-butadienes ;  carbonyllithium ;  carbolithiation ;  lithioketimines
刊名: PURE AND APPLIED CHEMISTRY
发表日期: 2009-02-01
DOI: 10.1351/PAC-CON-08-08-04
卷: 81, 期:2, 页:235-246
收录类别: SCI ;  ISTP
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: Both intermolecular reactivities toward C-O and C-N unsaturated substrates and intramolecular reactions of various 1-lithio-1,3-dienes are briefly summarized. Results reveal that intramolecular synergy between the alkenyllithium moiety and the butadienyl skeleton make 1-lithio-1,3-diene derivatives useful and unique as building blocks in organic synthesis. It is demonstrated that substitution patterns and the nature of the substituents on the butadienyl skeleton have remarkable effects on reaction pathways.
关键词[WOS]: FISCHER CARBENE COMPLEXES ;  DEAROMATIZING ANIONIC CYCLIZATION ;  TRANSITION-METAL-COMPLEXES ;  EFFICIENT SYNTHESIS ;  CARBON-MONOXIDE ;  CYCLOPENTADIENE DERIVATIVES ;  ELECTROPHILIC CYCLIZATION ;  STEREOSELECTIVE-SYNTHESIS ;  SKELETAL REARRANGEMENT ;  BENZOPYRANYLIDENETUNGSTEN(0) COMPLEXES
语种: 英语
WOS记录号: WOS:000263531100007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141465
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China

Recommended Citation:
Zhang, Wen-Xiong,Xi, Zhenfeng. 1-Lithio-1,3-dienes as useful building blocks in organic synthesis[J]. PURE AND APPLIED CHEMISTRY,2009,81(2):235-246.
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