DICP OpenIR
Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)
Kong, Yu-Xia1; Di, You-Ying1; Zhang, Ya-Qian1; Yang, Wei-Wei1; Tan, Zhi-Cheng2
Keyword1-dodecylamine Hydrochloride X-ray Crystallography Lattice Potential Energy Isoperibol Solution-reaction Calorimetry Enthalpy Of Dissolution Hydration Enthalpy
Source PublicationTHERMOCHIMICA ACTA
2009-11-10
DOI10.1016/j.tca.2009.05.015
Volume495Issue:1-2Pages:33-37
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS Research AreaChemistry
WOS KeywordTEMPERATURE HEAT-CAPACITIES ; STANDARD MOLAR ENTHALPY ; THERMODYNAMICS ; LATTICE ; CALORIMETRY ; CHLORIDE ; VOLUMES ; METAL
AbstractCrystal structure of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s) has been determined by an X-ray crystallography. Lattice potential energy and the molar volumes of the solid compound and its cation were respectively obtained. The enthalpy of dissolution of the compound was measured by an isoperibol solution-reaction calorimeter at 298.15 K. The molar enthalpy of dissolution at infinite dilution was determined to be Delta(s)H(m)(theta) = 30.36 kJ mol(-1), and relative apparent molar enthalpies (Phi(L)) relative partial molar enthalpies (L(2)) Of the compound and relative partial molar enthalpies (L(1)) of the solvent (double distilled water) at different concentrations in (mol kg(-1)) were obtained through fitted multiple regression equation by means of Pitzer's theory. Finally, hydration enthalpies of the substance and its cation were calculated by designing a thermochemical cycle in accordance with lattice potential energy and the molar enthalpy of dissolution at infinite dilution (Delta(s)H(m)(theta)). (C) 2009 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000271926200006
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141495
Collection中国科学院大连化学物理研究所
Affiliation1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252029, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Kong, Yu-Xia,Di, You-Ying,Zhang, Ya-Qian,et al. Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)[J]. THERMOCHIMICA ACTA,2009,495(1-2):33-37.
APA Kong, Yu-Xia,Di, You-Ying,Zhang, Ya-Qian,Yang, Wei-Wei,&Tan, Zhi-Cheng.(2009).Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s).THERMOCHIMICA ACTA,495(1-2),33-37.
MLA Kong, Yu-Xia,et al."Crystal structure and thermochemical properties of 1-dodecylamine hydrochloride (C(12)H(28)NCl)(s)".THERMOCHIMICA ACTA 495.1-2(2009):33-37.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Kong, Yu-Xia]'s Articles
[Di, You-Ying]'s Articles
[Zhang, Ya-Qian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Kong, Yu-Xia]'s Articles
[Di, You-Ying]'s Articles
[Zhang, Ya-Qian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Kong, Yu-Xia]'s Articles
[Di, You-Ying]'s Articles
[Zhang, Ya-Qian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.