DICP OpenIR
Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell
Zhou, Jinglin1; Zhang, Xiongfu1; Zhang, Jian1; Liu, Haiou1; Zhou, Li2; Yeung, KingLun3
KeywordCore-shell Catalyst Nickel Catalyst Fuel Cell Methane Steam Reforming Catalyst Deactivation Zeolite Membrane
Source PublicationCATALYSIS COMMUNICATIONS
2009-08-25
DOI10.1016/j.catcom.2009.06.002
Volume10Issue:14Pages:1804-1807
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical
WOS Research AreaChemistry
WOS KeywordPOROUS CERAMIC MEMBRANES ; PERMEATION PROPERTIES ; SYNTHESIS PARAMETERS ; GROWTH ; MCFC ; MICROSTRUCTURE ; ISOPARAFFINS ; H-2
AbstractA thin layer of silicalite-1 zeolite membrane was grown on the surface of Ni/SiO(2) and Ni/Al(2)O(3) catalyst beads after seeding and secondary regrowth to create core-shell catalysts that are resistant to alkali poisoning from direct internal reforming-mol ten carbonate fuel cell (DIR-MCFC). The zeolite shell thickness was optimized to prevent poisoning and minimize diffusion resistance. An out-of-cell test was designed to simulate the fuel cell operating conditions, which showed that the new core-shell catalysts maintained a high activity similar to the original fresh catalyst in spite of the exposure to alkali vapor at high temperature. The conventional Ni/SiO(2) and Ni/Al(2)O(3) catalysts suffered higher than 80% decrease in activity for steam reforming of methane reaction (SRM). (c) 2009 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000269664200005
Citation statistics
Cited Times:27[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141519
Collection中国科学院大连化学物理研究所
Affiliation1.Dalian Univ Technol, State Key Lab Fine Chem, Sch Chem Engn & Technol, Dalian 116012, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell Res & Dev Ctr, Dalian 116023, Peoples R China
3.Hong Kong Univ Sci & Technol, Dept Chem & Biomol Engn, Kowloon, Hong Kong, Peoples R China
Recommended Citation
GB/T 7714
Zhou, Jinglin,Zhang, Xiongfu,Zhang, Jian,et al. Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell[J]. CATALYSIS COMMUNICATIONS,2009,10(14):1804-1807.
APA Zhou, Jinglin,Zhang, Xiongfu,Zhang, Jian,Liu, Haiou,Zhou, Li,&Yeung, KingLun.(2009).Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell.CATALYSIS COMMUNICATIONS,10(14),1804-1807.
MLA Zhou, Jinglin,et al."Preparation of alkali-resistant, Sil-1 encapsulated nickel catalysts for direct internal reforming-molten carbonate fuel cell".CATALYSIS COMMUNICATIONS 10.14(2009):1804-1807.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Zhou, Jinglin]'s Articles
[Zhang, Xiongfu]'s Articles
[Zhang, Jian]'s Articles
Baidu academic
Similar articles in Baidu academic
[Zhou, Jinglin]'s Articles
[Zhang, Xiongfu]'s Articles
[Zhang, Jian]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Zhou, Jinglin]'s Articles
[Zhang, Xiongfu]'s Articles
[Zhang, Jian]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.