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题名: The Practical Synthesis of Double Axial Chiral Guanidines
作者: Guo, Qun-Sheng2;  Du, Da-Ming1, 2
关键词: Guanidine ;  chiral catalyst ;  organic base ;  synthesis
刊名: LETTERS IN ORGANIC CHEMISTRY
发表日期: 2009-04-01
卷: 6, 期:3, 页:197-202
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Two novel double axial chiral guanidines were designed according to the concept of double axial chirality. The practical synthetic procedures from (S)-1,1'-binaphthol have been developed. The title compounds were fully characterized by NMR, MS, IR and elemental analysis or HRMS. The two chiral guanidines can be interesting catalysts for asymmetric catalysis and preliminary asymmetric catalytic activity was investigated in Henry reaction and conjugate addition.
关键词[WOS]: THIOUREA BIFUNCTIONAL ORGANOCATALYST ;  ASYMMETRIC MICHAEL REACTION ;  HENRY NITROALDOL REACTION ;  BICYCLIC GUANIDINE ;  ENANTIOSELECTIVE SYNTHESIS ;  1,3-DICARBONYL COMPOUNDS ;  BASE CATALYST ;  NITROALKENES ;  SUPERBASES ;  ACRYLATE
语种: 英语
WOS记录号: WOS:000265798900004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141531
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China
2.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

Recommended Citation:
Guo, Qun-Sheng,Du, Da-Ming. The Practical Synthesis of Double Axial Chiral Guanidines[J]. LETTERS IN ORGANIC CHEMISTRY,2009,6(3):197-202.
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