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题名: Synthesis of furan from allenic sulfide derivatives
作者: Peng LingLing1;  Zhang Xiu1;  Ma Jie1;  Zhong ZhenZhen1;  Zhang Zhe1;  Zhang Yan1;  Wang JianBo1
关键词: furan ;  allene ;  synthetic method ;  nucleophilic reaction
刊名: SCIENCE IN CHINA SERIES B-CHEMISTRY
发表日期: 2009-10-01
DOI: 10.1007/s11426-009-0224-7
卷: 52, 期:10, 页:1622-1630
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: In this paper, we report the synthesis of furan derivatives from allenic sulfides. By the reaction with NaH, beta-Hydroxyl allenic sulfides were found to generate furan products in excellent yields with the removal of phenylthio group. beta-Aldehyde allenic sulfides were found to give similar furan products with one more substituent when treated with additional nucleophilic reagents. beta-ketone allenic sulfides can also cyclize to give furan derivatives with the promotion of P(2)O(5)
关键词[WOS]: C-BOND FORMATION ;  SUBSTITUTED FURANS ;  KETONES ;  REARRANGEMENT ;  CYCLIZATION ;  HETEROCYCLES ;  ALLENONES ;  ROUTE
语种: 英语
WOS记录号: WOS:000271168500012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141570
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

Recommended Citation:
Peng LingLing,Zhang Xiu,Ma Jie,et al. Synthesis of furan from allenic sulfide derivatives[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2009,52(10):1622-1630.
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