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题名: Enantioselective Synthesis of Chiral alpha-Aryl or alpha-Alkyl Substituted Ethylphosphonates via Rh-Catalyzed Asymmetric Hydrogenation with a P-Stereogenic BoPhoz-Type Ligand
作者: Wang, Dao-Yong1, 2;  Hu, Xiang-Ping1;  Deng, Jun1, 2;  Yu, Sai-Bo1, 2;  Duan, Zheng-Chao1, 2;  Zheng, Zhuo1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2009-06-05
DOI: 10.1021/jo900417m
卷: 74, 期:11, 页:4408-4410
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: An enantioselective synthesis of optically active 1-aryl or 1-alkyl substituted ethylphosphonates, based on the first Rh-catalyzed asymmetric hydrogenation of corresponding alpha,beta-unsaturated precursors with a P-stereogenic BoPhoz-type ligand under the mild condition, was developed, in which a wide range of 1-aryl or 1-alkyl substituted ethylphosphonates were achieved in up to 98% ee.
关键词[WOS]: PHOSPHINE-AMINOPHOSPHINE LIGANDS ;  PHOTO-ARBUZOV REARRANGEMENTS ;  ASPARTIC ACID ANTAGONISTS ;  PRACTICAL LIGANDS ;  AMINO-ACIDS ;  REACTIVE IMMUNIZATION ;  BENZYL PHOSPHITES ;  PHOSPHONATES ;  IRIDIUM ;  METHYL
语种: 英语
WOS记录号: WOS:000266545200062
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/141580
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Wang, Dao-Yong,Hu, Xiang-Ping,Deng, Jun,et al. Enantioselective Synthesis of Chiral alpha-Aryl or alpha-Alkyl Substituted Ethylphosphonates via Rh-Catalyzed Asymmetric Hydrogenation with a P-Stereogenic BoPhoz-Type Ligand[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(11):4408-4410.
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