DICP OpenIR
Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts
Liu, Huijuan1,2; Zhang, Ling1,2; Li, Xiujie1; Huang, Shengjun1; Liu, Shenglin1; Xin, Wenjie1; Xie, Sujuan1; Xu, Longya1
KeywordPropene 1-butene Metathesis 10wo(3)/al(2)o(3)-xhy Bifunction
Source PublicationJOURNAL OF NATURAL GAS CHEMISTRY
2009-09-01
DOI10.1016/S1003-9953(08)60113-9
Volume18Issue:3Pages:331-336
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS Keyword2-BUTENE ; ETHENE ; ISOMERIZATION ; ALUMINA
AbstractA new propene production route from 1-butene metathesis has been developed on heterogeneous 10WO(3)/Al(2)O(3)-HY catalysts with different HY contents. It is found that the catalysts play bi-functionally first for the isomerization of I-butene to 2-butene and then for the cross-metathesis between 1-butene and 2-butene to propene and 2-pentene. The combination of HY zeolite and Al(2)O(3) is prerequisite for the production of propene. The propene yield keeps increasing with the HY content in the range of 10-70 wt%, where 10WO(3)/Al(2)O(3)-70HY exhibits the highest propene yield. The MS-H(2)-TPR and MS-O(2)-TPO characterizations indicate that the increase of HY content in the catalysts weakens the interaction between W species and supports, whereas enhance the probability of coking on the metal species and acid sites.
Language英语
WOS IDWOS:000271072500012
Citation statistics
Cited Times:41[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141591
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Liu, Huijuan,Zhang, Ling,Li, Xiujie,et al. Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts[J]. JOURNAL OF NATURAL GAS CHEMISTRY,2009,18(3):331-336.
APA Liu, Huijuan.,Zhang, Ling.,Li, Xiujie.,Huang, Shengjun.,Liu, Shenglin.,...&Xu, Longya.(2009).Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts.JOURNAL OF NATURAL GAS CHEMISTRY,18(3),331-336.
MLA Liu, Huijuan,et al."Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts".JOURNAL OF NATURAL GAS CHEMISTRY 18.3(2009):331-336.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Liu, Huijuan]'s Articles
[Zhang, Ling]'s Articles
[Li, Xiujie]'s Articles
Baidu academic
Similar articles in Baidu academic
[Liu, Huijuan]'s Articles
[Zhang, Ling]'s Articles
[Li, Xiujie]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Liu, Huijuan]'s Articles
[Zhang, Ling]'s Articles
[Li, Xiujie]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.