DICP OpenIR
Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands
Duan, Zheng-Chao1,2; Hu, Xiang-Ping1; Zhang, Cheng1,2; Wang, Dao-Yong1,2; Yu, Sai-Bo1,2; Zheng, Zhuo1
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2009-12-04
DOI10.1021/jo901619c
Volume74Issue:23Pages:9191-9194
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordENOL ESTER PHOSPHONATES ; PHOSPHINE-PHOSPHORAMIDITE LIGANDS ; ALPHA-AMINOPHOSPHONIC ACIDS ; ASYMMETRIC HYDROGENATION ; ALPHA,BETA-UNSATURATED PHOSPHONATES ; SUBSTITUTED ETHYLPHOSPHONATES ; STEREOSELECTIVE-SYNTHESIS ; REACTIVE IMMUNIZATION ; PRACTICAL LIGANDS ; MICELLAR MEDIA
AbstractAn enantioselective synthesis of chiral alkylphosphonates bearing a beta-stereogenic center, based on the Rh-catalyzed asymmetric hydrogenation of corresponding beta-substituted beta,gamma-unsaturated phosphonates with a Ferrocene-based monophosphoramidite ligand Under the mild hydrogenation conditions, was developed, in which an ee value of up to 98% was obtained.
Language英语
WOS IDWOS:000272083700033
Citation statistics
Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/141598
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Duan, Zheng-Chao,Hu, Xiang-Ping,Zhang, Cheng,et al. Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(23):9191-9194.
APA Duan, Zheng-Chao,Hu, Xiang-Ping,Zhang, Cheng,Wang, Dao-Yong,Yu, Sai-Bo,&Zheng, Zhuo.(2009).Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands.JOURNAL OF ORGANIC CHEMISTRY,74(23),9191-9194.
MLA Duan, Zheng-Chao,et al."Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands".JOURNAL OF ORGANIC CHEMISTRY 74.23(2009):9191-9194.
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