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Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands
Duan, Zheng-Chao1,2; Hu, Xiang-Ping1; Zhang, Cheng1,2; Wang, Dao-Yong1,2; Yu, Sai-Bo1,2; Zheng, Zhuo1
刊名JOURNAL OF ORGANIC CHEMISTRY
2009-12-04
DOI10.1021/jo901619c
74期:23页:9191-9194
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ENOL ESTER PHOSPHONATES ; PHOSPHINE-PHOSPHORAMIDITE LIGANDS ; ALPHA-AMINOPHOSPHONIC ACIDS ; ASYMMETRIC HYDROGENATION ; ALPHA,BETA-UNSATURATED PHOSPHONATES ; SUBSTITUTED ETHYLPHOSPHONATES ; STEREOSELECTIVE-SYNTHESIS ; REACTIVE IMMUNIZATION ; PRACTICAL LIGANDS ; MICELLAR MEDIA
英文摘要An enantioselective synthesis of chiral alkylphosphonates bearing a beta-stereogenic center, based on the Rh-catalyzed asymmetric hydrogenation of corresponding beta-substituted beta,gamma-unsaturated phosphonates with a Ferrocene-based monophosphoramidite ligand Under the mild hydrogenation conditions, was developed, in which an ee value of up to 98% was obtained.
语种英语
WOS记录号WOS:000272083700033
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/141598
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Duan, Zheng-Chao,Hu, Xiang-Ping,Zhang, Cheng,et al. Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands[J]. JOURNAL OF ORGANIC CHEMISTRY,2009,74(23):9191-9194.
APA Duan, Zheng-Chao,Hu, Xiang-Ping,Zhang, Cheng,Wang, Dao-Yong,Yu, Sai-Bo,&Zheng, Zhuo.(2009).Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands.JOURNAL OF ORGANIC CHEMISTRY,74(23),9191-9194.
MLA Duan, Zheng-Chao,et al."Highly Enantioselective Rh-Catalyzed Hydrogenation of beta,gamma-Unsaturated Phosphonates with Chiral Ferrocene-Based Monophosphoramidite Ligands".JOURNAL OF ORGANIC CHEMISTRY 74.23(2009):9191-9194.
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